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single molecule electronics and devices单分子电子产品和设备
Sensors 2012, 12, 7259-7298; doi:10.3390/s120607259
OPEN ACCESS
sensors
ISSN 1424-8220
/journal/sensors
Review
Single Molecule Electronics and Devices
Makusu Tsutsui and Masateru Taniguchi *
The Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki,
Osaka 567-0047, Japan; E-Mail: makusu32@sanken.osaka-u.ac.jp
* Author to whom correspondence should be addressed; E-Mail: taniguti@sanken.osaka-u.ac.jp;
Tel.: +81-6-6879-4289; Fax: +81-6-6879-4286.
Received: 16 April 2012; in revised form: 15 May 2012 / Accepted: 17 May 2012 /
Published: 30 May 2012
Abstract: The manufacture of integrated circuits with single-molecule building blocks is a
goal of molecular electronics. While research in the past has been limited to bulk
experiments on self-assembled monolayers, advances in technology have now enabled us
to fabricate single-molecule junctions. This has led to significant progress in understanding
electron transport in molecular systems at the single-molecule level and the concomitant
emergence of new device concepts. Here, we review recent developments in this field. We
summarize the methods currently used to form metal-molecule-metal structures and
some single-molecule techniques essential for characterizing molecular junctions such
as inelastic electron tunnelling spectroscopy. We then highlight several important
achievements, including demonstration of single-molecule diodes, transistors, and switches
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