solid-state [2+2] photodimerization and photopolymerization of α,ω-diarylpolyene monomers effective utilization of noncovalent intermolecular interactions in crystals固态[2 + 2]光二聚α光聚合,ω-diarylpolyene单体有效利用共价分子间相互作用的晶体.pdfVIP

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solid-state [2+2] photodimerization and photopolymerization of α,ω-diarylpolyene monomers effective utilization of noncovalent intermolecular interactions in crystals固态[2 + 2]光二聚α光聚合,ω-diarylpolyene单体有效利用共价分子间相互作用的晶体.pdf

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solid-state[22]photodimerizationandphotopolymerizationofα,ω-diarylpolyenemonomerseffectiveutilizationofnoncovalentintermolecularinteractionsincrystals固态[22]光二聚α光聚合,ω-diarylpolyene单体有效利用共价分子间相互作用的晶体

Molecules 2011, 16, 119-148; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Review Solid-State [2+2] Photodimerization and Photopolymerization of αα,ωω-Diarylpolyene Monomers: Effective Utilization of αα ωω Noncovalent Intermolecular Interactions in Crystals Yoriko Sonoda Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Higashi 1-1-1, Tsukuba, Ibaraki 305-8565, Japan; E-Mail: y.sonoda@aist.go.jp; Tel.: +81-29-861-6390; Fax: +81-29-861-4673. Received: 25 November 2010; in revised form: 17 December 2010 / Accepted: 24 December 2010 / Published: 28 December 2010 Abstract: [2+2] Photocycloaddition of olefins is a very useful reaction in synthetic organic chemistry to obtain cyclobutane-containing molecules, which are almost inaccessible by other methods. The reaction, when performed in the crystalline state, occurs more efficiently and selectively than in homogeneous solution due to tight and regular molecular arrangement in the crystal state. Despite numerous examples for the solid-state [2+2] photodimerization of monoenes, however, it is still a challenge to prepare not only dimers but also higher oligomers and polymers from conjugated polyenes, which have multiple reactive double bonds in a molecule. In our recent studies of the solid-state photoreactions of α,ω-diarylpolyenes, noncovalent intermolecular interactions in crystals were effectively utilize