solvent effects on nuclear magnetic resonance 2j(c,hf) and 1j(c,hf) spin–spin coupling constants in acetaldehyde溶剂对核磁共振的影响2 j(c,高频)和1(c hf)自旋自旋耦合常数乙醛.pdfVIP
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solvent effects on nuclear magnetic resonance 2j(c,hf) and 1j(c,hf) spin–spin coupling constants in acetaldehyde溶剂对核磁共振的影响2 j(c,高频)和1(c hf)自旋自旋耦合常数乙醛
Int. J. Mol. Sci. 2003, 4, 93-106
International Journal of
Molecular Sciences
ISSN 1422-0067
© 2003 by MDPI
/ijms/
Solvent Effects on Nuclear Magnetic Resonance 2J(C,H ) and
f
1J(C,H ) Spin–Spin Coupling Constants in Acetaldehyde
f
1 2 2 2 1
Daniel Zaccari, Verónica Barone, Juan E. Peralta, Rubén H. Contreras*, Oscar E. Taurian,
Ernesto Díez3 and Angel Esteban4
1 Departamento de Química y Física, FCEF-QyN Universidad Nacional de Río Cuarto, Ruta Nac. 36,
Km 601, (5800) Río Cuarto, Argentina.
2 Departamento de Física, FCEyN, Universidad de Buenos Aires and CONICET, Ciudad Universitaria,
Pab. 1, (1428), Buenos Aires, Argentina.
3 Departamento de Química Física Aplicada, Facultad de Ciencias C2. Universidad Autónoma de
Madrid, E-28049, Madrid, Spain;
4 Departamento de Química Física, Facultad de Ciencias, Universidad de Alicante, E-03080 Alicante,
Spain.
* Corresponding author. Tel.: +54 11 4576 3353, Fax: +54 11 4576-3357, E-mail: contrera@df.uba.ar,
URL: http://www.df.uba.ar/~juanp/
Received: 1 July 2002 / Accepted: 22 August 2002 / Published: 25 February 2003
Abstract: The known solvent dependence of 1J(C ,H ) and 2J(C ,H ) couplings
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