study of voltammetric determination of carcinogenic 1-nitropyrene and 1-aminopyrene using a glassy carbon paste electrode研究伏安测定致癌1-nitropyrene和1-aminopyrene使用玻璃碳糊电极.pdfVIP
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study of voltammetric determination of carcinogenic 1-nitropyrene and 1-aminopyrene using a glassy carbon paste electrode研究伏安测定致癌1-nitropyrene和1-aminopyrene使用玻璃碳糊电极
Sensors 2004, 4, 47-57
sensors
ISSN 1424-8220
© 2004 by MDPI
/sensors
Study of Voltammetric Determination of Carcinogenic
1-Nitropyrene and 1-Aminopyrene Using a Glassy Carbon Paste
Electrode
1 * 2 3 1
Jirí Barek , Alexandr Muck , Joseph Wang and Jirí Zima
1 UNESCO Laboratory of Environmental Electrochemistry, Department of Analytical Chemistry,
Charles University, 128 43 Prague 2, Czech Republic
2 Max-Planck Institute for Chemical Ecology, Hans-Knoell-Str.8, 07745 Jena, Germany
3 SensoChip Laboratory, Department of Chemistry and Biochemistry, New Mexico State University,
MSC 3C, Las Cruces, NM 88003, USA
* Author to whom correspondence should be addressed. E-mail: barek@natur.cuni.cz
Received: 30 April 2004 / Accepted: 30 May 2004 / Published: 20 July 2004
Abstract: Linear scan voltammetry (LSV), differential pulse voltammetry (DPV) and
voltammetry with adsorptive accumulation (AAV) at a glassy carbon paste electrode
(GCPE) based on mixing glassy carbon spherical microparticles with an organic pasting
liquid were used for the determination of trace amounts of carcinogenic 1-nitropyrene (1-
NP) (the limit of determination around 2.10-5 mol L-1 for LSV and 2.10-6 mol L-1 for DPV)
and 1-aminopyrene (1-AP) (the limit of determination around 3.10-6 mol L-1 for LSV,
-6 -1 -7 -1
1.10 mol L for DPV and 1.10 mol
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