synthesis and properties of octithiophene dication sterically segregated by annelation with bicyclo[2.2.2]octene units的合成和性质octithiophene双阳离子sterically隔离通过annelation bicyclo(2.2.2)辛烯单元.pdfVIP

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synthesis and properties of octithiophene dication sterically segregated by annelation with bicyclo[2.2.2]octene units的合成和性质octithiophene双阳离子sterically隔离通过annelation bicyclo(2.2.2)辛烯单元.pdf

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synthesis and properties of octithiophene dication sterically segregated by annelation with bicyclo[2.2.2]octene units的合成和性质octithiophene双阳离子sterically隔离通过annelation bicyclo(2.2.2)辛烯单元

Materials 2010, 3, 2037-2052; doi:10.3390/ma3032037 OPEN ACCESS materials ISSN 1996-1944 /journal/materials Article Synthesis and Properties of Octithiophene Dication Sterically Segregated by Annelation with Bicyclo[2.2.2]octene Units 1, 2,† 1 1 Tohru Nishinaga *, Daisuke Yamazaki , Masaki Tateno , Masahiko Iyoda and Koichi Komatsu 2,§ 1 Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan; E-Mails: tateno-masaki@ed.tmu.ac.jp (M.T.); iyoda@tmu.ac.jp (M.I.) 2 Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan; E-Mails: yamazaki.daisuke@me.m-kagaku.co.jp (D.Y.); komatsu@fukui-ut.ac.jp (K.K.) † Present address: Mitsubishi Chemical Corporation, 1000, Kamoshida-cho Aoba-ku, Yokohama, Kanagawa 227-0033, Japan. § Present address: Department of Environmental and Biological Chemistry, Fukui University of Technology, Gakuen, Fukui 910-8505, Japan. * Author to whom correspondence should be addressed; E-Mail: nishinaga-tohru@tmu.ac.jp; Tel.: +81-42-677-2546; Fax: +81-42-677-2525. Received: 29 January 2010; in revised form: 13 February 2010 / Accepted: 16 March 2010 / Published: 19 March 2010 Abstract: Octithiophene sterically segregated by annelation with bicyclo[2.2.2]octene (BCO) units was synthesized to study the unimolecular properties of longer oligothiophene dications. For the preparation of such longer oligomers, a ne