synthesis, crystal structure and luminescent property of mg(ii) complex with n-benzenesulphonyl-l-leucine and 1,10-phenanthroline合成、晶体结构和发光性质n-benzenesulphonyl-l-leucine和1毫克(ii)复杂,10-phenanthroline.pdfVIP
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synthesis, crystal structure and luminescent property of mg(ii) complex with n-benzenesulphonyl-l-leucine and 1,10-phenanthroline合成、晶体结构和发光性质n-benzenesulphonyl-l-leucine和1毫克(ii)复杂,10-phenanthroline
Materials 2012, 5, 558-565; doi:10.3390/ma5040558
OPEN ACCESS
materials
ISSN 1996-1944
/journal/materials
Article
Synthesis, Crystal Structure and Luminescent Property of
Mg(II) Complex with N-Benzenesulphonyl-L-Leucine
and 1,10-Phenanthroline
Xishi Tai *, Na Wei and Donghao Wang
College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, China;
E-Mails: wanglihua929@163.com (N.W.); wftaixs@163.com (D.W.)
* Author to whom correspondence should be addressed; E-Mail: taixs@;
Tel.: +86-536-8785363; Fax: +86-536-8785363.
Received: 7 February 2012; in revised form: 12 March 2012 / Accepted: 16 March 2012 /
Published: 23 March 2012
Abstract: A new complex [Mg(L) (phen)(H O) ](phen)(H O) [L= N-benzenesulphonyl-
2 2 2 2 2
L-leucine] was synthesized by the reaction of magnesium chloride hexahydrate with
N-benzenesulphonyl-L-leucine and 1,10-phenanthroline in the CH CH OH/H O (v:v = 5:1).
3 2 2
It was characterized by elemental analysis, IR and X-ray single crystal diffraction analysis.
The crystal of the title complex [Mg(L) (phen)(H O) ](phen)(H O) belongs to triclinic,
2 2 2 2 2
space group P-1 with a = 0.72772(15) nm, b = 1.4279(3) nm, c = 1.4418(3) nm,
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