多层核壳型聚吡咯二氧化矽包覆镍锌铁氧磁体奈米复材之制备及其电磁.docVIP

中文摘要 本論文係利用溶膠-凝膠燃燒與St?ber法，合成核殼型二氧化矽(SiO2)/鎳-鋅鐵氧磁體(Ni-Zn ferrite)先驅物。 再以CTAB及CSA為界面活性劑，於酸性環境下行原位聚合反應，製備聚吡咯(PPy)/SiO2/Ni-Zn ferrite之奈米複材。 結果顯示，以St?ber method可成功製備以Ni-Zn ferrite為核、SiO2為殼之核殼型SiO2/Ni-Zn ferrite奈米複材，其殼層厚度隨四乙基矽氧烷(TEOS)的增加而增加，厚度為10至25 nm；PPy/SiO2/Ni-Zn ferrite複材則呈不規則之多層核殼結構，其形貌與界面活性劑濃度及種類有關。 磁性量測結果顯示，核殼型SiO2/Ni-Zn ferrite或多層核殼型PPy/SiO2/Ni-Zn ferrite複材主要磁特性源自Ni-Zn ferrite，煆燒程序可有效提昇Ni-Zn ferrite之磁特性。 當煆燒溫度為1400℃時，其飽和磁化量(Ms)與導磁損耗在高頻部分有明顯的上昇，但隨TEOS添加量、Py單體濃度的增加而降低。 多層核殼型PPy/SiO2/Ni-Zn ferrite複材之導電度與PPy附著量呈正比。 介電量測結果顯示，外層包覆SiO2殼層之SiO2/Ni-Zn ferrite奈米複材，Ms與複介電常數會降低，但其介電損耗卻較Ni-Zn ferrite為高。 以CTAB作為界面活性劑製備之多層核殼型PPy/SiO2/Ni-Zn ferrite奈米複材，於300 MHz時有最大之介電損耗(其tan δ = 0.76)，顯示此多層核殼複材在1.8 GHz以下有較佳的介電損耗。 英文摘要 Polypyrrole coated-silica/Ni-Zn ferrite(PPy/SiO2/Ni-Zn ferrite) composites were synthesized by an in-situ polymerization method, where pyrrole (Py), cetyltrimethyl ammonium brombide (CTAB), camphorsulfonic acid(CSA) and SiO2/Ni-Zn ferrite nanoparticle act as monomer, surfactant and nuclear, respectively, in which the SiO2/Ni-Zn ferrite nanoparticle was prepared by the combination of the combustion and the modified St?ber method. Results showed that the thickness of silica coating on the surface of Ni-Zn ferrites nanoparticles increased gradually with increasing the tetraethylorthosilicate (TEOS) content. The PPy/SiO2/Ni-Zn ferrite composite revealed a multilayer core-shell structure, where PPy is the outer shell of the composite with irregular morphology. The morphology of PPy/SiO2/Ni-Zn ferrite composite is attributed to the surfactant/monomer molar ratio. For the room- temperature SQUID analysis, the magnetic properties of PPy/SiO2/Ni-Zn ferrite and SiO2/Ni-Zn ferrite nanocomposites are mainly dominated by Ni-Zn ferrite nanoparticle. As the calcination temperature at 1400℃, the saturation magnetization(Ms) and magnetic loss(tan δμ) are significantly enhanced at high frequency, the values of Ms and tan δμ decreased with the increasing TEOS and Py content. As for 4