香鳞毛蕨中 1 个新的色原酮苷（II）.PDFVIP

·2136 · 中草药 Chinese Traditional and Herbal Drugs 第 45 卷 第 15 期 2014 年 8 月 香鳞毛蕨中 1 个新的色原酮苷 （II ） 1 2 1 1 1 1* 彭 冰 ，高增平 ，何 薇 ，王 宏 ，韩旭阳 ，曾祖平 1. 首都医科大学附属北京中医医院 北京市中医研究所，北京 100010 2. 北京中医药大学中药学院，北京 100102 摘 要：目的 研究香鳞毛蕨 Dryopteris fragrans 全草的化学成分。方法 采用各种柱色谱方法分离，通过理化鉴别及波谱 分析技术鉴定化合物的结构。结果 从香鳞毛蕨全草水提取物中分离得到 3 个化合物，分别鉴定为 2-异丙基-5, 7-二羟基- 1′-O-β-D-吡喃葡萄糖基色原酮苷（1）、(6R, 9R)-3-酮-α-紫罗兰醇-9-O-β-D-吡喃葡萄糖苷（2 ）和红豆杉苷（3 ）。结论 化合 物 1 为新化合物，命名为香蕨色原酮 B ，化合物2 和 3 为首次从该科植物中分离得到。 关键词：香鳞毛蕨；2-异丙基-5, 7-二羟基-1′-O-β-D-吡喃葡萄糖基色原酮苷；香蕨色原酮 B ；(6R, 9R)-3-酮-α-紫罗兰醇-9-O-β-D- 吡喃葡萄糖苷；红豆杉苷 中图分类号：R284.1 文献标志码：A 文章编号：0253 - 2670(2014)15 - 2136 - 03 DOI: 10.7501/j.issn.0253-2670.2014.15.003 A new chromone glycoside from Dryopteris fragrans (II) 1 2 1 1 1 1 PENG Bing , GAO Zeng-ping , HE Wei , WANG Hong , HAN Xu-yang , ZENG Zu-ping 1. Beijing Institute of Traditional Chinese Medicine, Beijing Hospital of Traditional Chinese Medicine Affiliated to Capital Medical University, Beijing 100010, China 2. School of Chinese Materia Medica, Beijing University of Traditional Chinese Medicine, Beijing 100102, China Abstract: Objective To study the chemical constituents from the whole plants of Dryopteris fragrans . Methods The chemical constituents were isolated by various column chromatographic methods. The structures of the compounds were elucidated on the basis of physiochemical properties and spectral analyses. Results Three compounds named 2-isopropyl-5, 7-dihydroxy-1′-O-β-D- glucopyranosyl chromone (1), (6R, 9R)-3-oxo-α-ionol-9-O-β-D-glucopyranoside (2), and taxicatin (3) were isolated and identified. Conclusion Compound 1 is a new compound named frachromone B, compounds 2 and 3 are reported for the first time from family Dryopteridaceae. Key wo