the synthesis of some perhydrobenzimidazolinium salts and their application in pd-carbene catalyzed heck and suzuki reactions一些perhydrobenzimidazolinium盐的合成及其应用pd-carbene催化和铃木反应.pdfVIP

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the synthesis of some perhydrobenzimidazolinium salts and their application in pd-carbene catalyzed heck and suzuki reactions一些perhydrobenzimidazolinium盐的合成及其应用pd-carbene催化和铃木反应.pdf

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the synthesis of some perhydrobenzimidazolinium salts and their application in pd-carbene catalyzed heck and suzuki reactions一些perhydrobenzimidazolinium盐的合成及其应用pd-carbene催化和铃木反应

Molecules 2009, 14, 2032-2042; doi:10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article The Synthesis of Some Perhydrobenzimidazolinium Salts and Their Application in Pd-Carbene Catalyzed Heck and Suzuki Reactions Murat Yiğit Department of Chemistry, Faculty of Science and Art, Adıyaman University, 02040 Adıyaman, Turkey; E-Mail: myigit@.tr; Fax: +90 416 223 1774 Received: 13 May 2009; in revised form: 27 May 2009 / Accepted: 3 June 2009 / Published: 5 June 2009 Abstract: Novel 1,3-dialkylperhydrobenzimidazolinium chloride salts were prepared as precursors of N-heterocyclic carbenes 3a-e by reacting N,N’-dialkylcyclohexandiamine, triethyl orthoformate and ammonium chloride. The salts were characterized spectroscopically and the complexes formed in situ from Pd(OAc) and 3 have been tested 2 as catalysts in homogenous Heck and Suzuki reactions. Keyword: Heck and Suzuki reactions; perhydrobenzimidazolinium salt; palladium; carbene; catalyst 1. Introduction Palladium-catalyzed C-C bond formation is one of the most fundemental and important reactions in modern synthetic chemistry [1,2]. It represents the key the step in a wide range of preparative organic processes, from the synthesis of natural products [3] to supramolecular chemistry and material science [4]. Common methodologies used are the palladium mediated coupling of the organic halides or halide