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氢氰酸泄漏事故现场处置方案(Hydrocyanic acid leakage accident disposal site)
氢氰酸泄漏事故现场处置方案(Hydrocyanic acid leakage accident disposal site)
Hydrocyanic acid leakage accident disposal site
I. Basic Characteristics
1, logo
Name: Chinese hydrocyanic acid
English Name: Hydrocyanicacid
2, physical and chemical properties
Appearance and shape: colorless transparent liquid, bitter almond flavor, volatile
Main applications: used in making acrylonitrile, acrylic resin and insecticide etc.
Melting point (DEG C): -13.4 relative density (water = 1): 0.69 (lighter than water)
Boiling point (Celsius): 25.7 relative density (air = 1): 0.93 (lighter than air)
Saturated vapor pressure (KPa): 53.33/9.8 DEG C
Solubility: miscible with water, miscible with ethanol, ether, glycerin, benzene, chloroform
Critical temperature (c): 183.5 critical pressure (MPa): 4.95
Combustion heat (KJ/mol): minimum ignition energy (mJ):
Two, hazard characteristics
1, combustion explosion risk
Flammability: Flammability rating: fire rating: a.
Flash point (DEG): 17.8 explosion limit (V%): 5.6
Self ignition temperature (DEG C): 538 explosion upper limit (V%): 40
Hazard characteristics: explosive mixture formed with air, which can cause combustion explosion when exposed to fire and high heat. In case of high fever, possible polymerization reaction, the emergence of a large number of exothermic phenomenon caused by vessel rupture and explosion.
Combustion (decomposition) products: hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide
Stability: stability, avoid contact conditions: light
Aggregation hazards: can occur
Banned substances: strong oxidizing agents, alkalis
2, diffusion
Liquidity and volatility.
3, toxicity and health hazard
Routes of invasion: inhalation, ingestion, percutaneous absorption
Toxicity: high toxicity.
Health hazard: inhibition of respiratory enzymes. High concentrations of inhalation can cause sudden death. The non sudden clinical manifestations can be divided into 4 stages: prodromal stage mucosa stimulation, breathing deeply, fatigue, headache,
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