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汪小兰有机化学第四版10-17章答案(Wang Xiaolan organic chemistry, Fourth Edition, 10-17 chapters)
汪小兰有机化学第四版10-17章答案(Wang Xiaolan organic chemistry, Fourth Edition, 10-17 chapters)
The tenth chapter: carboxylic acid and its derivatives
10.1 with the system name (such as please note) or write structure
Answer: A. 2 - methyl propionic acid B., salicylic acid (Shui Yangsuan) C. 2 - Ding Xisuan
D 3 - bromo butyric acid e., butyl chloride F., butyric acid anhydride g., ethyl propionate H., propyl acetate Propyl, acetate
I. benzamide J. maleic acid
10.2 arrange the following compounds in order of acidity:
A., CH3CH2CHBrCO2H, B., CH3CHBrCH2CO2H, C., CH3CH2CH2CO2H
D., CH3CH2CH2CH2OH, e., C6H5OH, F., H2CO3, g., Br3CCO2H, H2O, H.
Answer: acid sort g a C F e H D B
10.3 write down the main products of the following reactions
Answer:
10.4 identify the following compounds with simple chemical methods:
Answer:
A. KmnO4 B. FeCl3 C. Br2 or KmnO4 D. FeCl3 2 2,4- two 4-dinitrophenylhydrazine or I2 / NaOH
10.5 complete the following transformation:
Answer:
10.6 how to separate the mixture of hexyl alcohol, caproic acid and methyl phenol to obtain various pure components?
Answer:
10.7 write out various isomers of unsaturated two element carboxylic acid with molecular formula of C5H6O4. If geometrically heterogeneous, be marked with Z, E, and indicate which anhydride is easy to form.
Answer:
(Z) Yi Chenggan (E) is difficult to (Z) Yi Chenggan (E), not easy to form anhydride
10.8 compound A, formula C4H6O4,
After heating, the B with molecular formula of C4H4O3 is obtained and the A is heated with the excess methanol and a small amount of sulfuric acid to form a C with molecular formula of C6H10O4. B also acts as an C in excess of methanol. After the interaction of A with LiAlH4, the molecular formula is C4H10O2 D. Write the structures of A, B, C, D, and their reactions to each other.
Answer:
The eleventh chapter replaces acid
11.1 write the structural formula or nomenclature of the following compounds.
M. n.
Answer:
M., 3--, butyric acid (3--Chlorobutanoic, acid), N., 4--, oxy v
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