青海某低品位难选铅锌矿石合理选矿流程的探索-有色金属科学与工程.DOC

青海某低品位难选铅锌矿石合理选矿流程的探索 方夕辉 丛 颖 朱冬梅 庄杜娟 （江西理工大学资源与环境工程学院，江西赣州，341000） 摘 要：青海某铅锌矿铅锌品位低，铅矿物与锌硫矿物共生关系密切，属于难选低品位铅锌矿石，本文采用优先浮选工艺方案对该矿石进行了小型试验。试验结果表明，优先浮选工艺方案利用铅矿物与锌硫矿物可浮性差异较大的特点，采用石灰、亚硫酸钠和硫酸锌等抑制锌硫，以乙硫氮为铅捕收剂，进行铅矿物优先浮选，选铅尾矿脱水后调节矿浆pH值至10.5左右，用硫酸铜作为活化剂来活化铁闪锌矿选锌，试验在原矿含铅2.27%，含锌1.17%的条件下，取得了铅精矿含铅50.87%，铅回收率为78.33%，锌精矿含锌45.30%，锌回收率为70.47%的技术指标。 关键词：铅锌矿；低品位；优先浮选；铁闪锌矿 The exploration of rational dressing flow sheet of a certain low-grade refractory lead-zinc-ores in Qinghai Province Fang Xihui，Cong Ying，Zhu Dongmei，Zhuang Dujuan School of Resource and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou，341000, China Abstract： lead-zinc ores in Qinghai belongs to low-grade refractory lead-zinc-ores because the content of lead and zinc are very low the lead minerals associated to zinc and sulfur minerals closely. According to the characteristic of the big floatability difference between lead minerals and zinc sulfur minerals, the selective flotation flow-sheet was adopted. Laboratory test adopted diethyl dithiocarbamate as the collector of lead ;lime ,sodium sulfite and zinc sulfate as the depressor of zinc sulfur minerals in lead roughing, then use copper sulfate as activator of marmatite after adjusting the PH value of the dehydration pulp of lead tailing to 6-7, the results showed that in the condition of raw ore with a lead and zinc grade 2.27% and 1.17% respectively ,the technical indicators of lead concentrate with lead grade 50.87% and lead recovery 78.33% and zinc concentrate with zinc grade 45.30% and zinc recovery 70.47% can be obtained from the closed-circuit test. Keywords： lead-zinc ores；low grade；sequential selective flotation；marmatite；pH 有色金属铅锌硫化矿是最为重要的铅锌有色金属矿产资源，我国铅锌金属的获得大多数来自于该类矿石[]。我国也是一个铅锌资源大国[]，但随着东部地区的铅锌矿产资源的日渐枯竭，矿山原料不足已经成为制约我国铅锌工业可持续发展的关键性因素[]。因此积极对低品位和难选铅锌矿石开展研究，提高该类矿石的资源利用率，对缓解我国铅锌资源紧张局面，拓展铅锌资源范围具有重要的意义。 富含铁闪锌矿和磁黄铁矿的铅锌矿石属于难选矿石[]，原因主要在于一是磁黄铁矿存在着单斜磁黄铁矿与六方磁黄铁矿同质多象变体，两者可浮性存在较大的差异，在同一分选条件下难以将磁黄铁矿完全与其它矿物分离[]；二是磁黄铁矿易于泥化和氧化，消耗矿浆中的氧气而