长江中下游成矿带斑岩型矿床的成矿作用周涛发(iagod2014).ppt

[22] In whole rock chemistry of these porphyries shows the early porphyry-skarn deposit porphyries intrusions are mainly high-K calc-alkaline, whereas the late porphyry deposits intrusions are mainly calc-alkaline (with higher Na). Some ore-bearing porphyries at Tongshankou, Shujiadian and Anjishan contain varible K, with some samples falling within the shoshonitic field, this has been attributed to K-feldspar alteration. * [23] All the ore-bearing porphyries in the MLYB have similar adakite affinity in their Sr-Y and Yb (ytterbium) compositions. * [24] Fluid inclusion analysis show that the early porphyry ore-forming fluid comprises mainly CO2 and H2O except the late stage sulfide-carbonate. * [25] The late porphyry-the Shaxi deposit fluid inclusions contain SO2 and H2O. * [26] We see a lot of hydrothermal breccia, breccia cemented by hydrothermal minerals including sulfides in the early porphyry deposits. What does it mean? * [27] There are many types of fluid inclusions in the Shujiadian minerals, multi-phase inclusion with CO2 gas, daughter mineral-halite and sulfides, we also see pure gas and pure water fluid inclusions with the same homogenlized temperature. Micro themometry Investigations on the fluid inclusions in Shujiadian deposit indicate that the ore-forming fluids of the early porphyry had gone through: immiscibility at the early stage, and boiling in the quartz-sulfide stage. At the sulfide-carbonate stage meteoric water mixed with the magmatic fluid. * [28] Similar processes might have happened for the late porphyry deposit. We can see the K-feldspar altered breccia cemented by hydrothermal minerals. * [29] The ore-forming fluids of the late porphyry also went through immiscibility at the K-feldspar stage, boiling at the quartz-sulfide stage and mixing with meteoric water at the quartz-carbonate stage, similar to the Shujiadian deposit. * [30] Oxygen isotope composition indicates that ore-forming fluids of both the early and late porphyry were formed