有机染料靛蓝的合成和应用.PDF

大学化学(Daxue Huaxue) April Univ. Chem. 2016, 31 (4), 83－88 83 ∙国外化学教育∙ doi: 10.3866/PKU.DXH 有机染料靛蓝的合成与应用 ——介绍一个国外本科生实验并讨论其相关问题 王志鹏* (清华大学化学系，北京100084；Department of Chemistry ，Texas AM University ，Texas 77840 ，USA) 摘要：介绍一个国外大学有机化学实验——有机染料靛蓝(Indigo)的合成，及后续比较其对于不同的合 成织物或天然纤维的染色情况。对实验中3 方面问题进行了分析讨论，而这在国外的实验教材中并没有 涉及到，即靛蓝合成过程的反应机理、靛蓝对纤维织物染色的原理以及关于靛蓝对纤维织物染色过程的 讨论。该实验的设计值得借鉴于国内本科生有机化学实验。 关键词：靛蓝；靛白；染料；纤维；本科生实验 中图分类号：O6 ；G64 The Synthesis and Application of an Organic Dye Indigo: Introduction and Discussion of an Oversea Undergraduate Experiment WANG A. Zhipeng* (Chemistry Department, Tsinghua University, Beijing 100084, P. R. China; Department of Chemistry, Texas AM University, Texas 77840, USA) Abstract: The synthesis of organic dye Indigo followed by the application on the coloration of different fiber structures is introduced, as an undergraduate organic experiment widely employed overseas. Three confusing but important questions related to the synthesis procedure are also discussed, which are normally not mentioned in foreign textbooks: the synthetic mechanism for Indigo, the principle of Indigo coloration, and the process design of Indigo dyeing. The exquisitely designed procedure and practical achievement of this experiment are both worth applying to the domestic undergraduate experiments. Key Words: Indigo; Leucoindigo/Indigo white; Organic dye; Fiber; Undergraduate experiment 与国内有机化学实验相比，国外的某些“实验目的”相对应的本科生有机化学实验设计更加结合 实际应用。这样的实验设计能够使学生将所学到的知识直接应用于实际生产与生活，并且直观地加深