改质沥青对电煅煤和沥青焦浸润性的研究.doc

改质沥青对电煅无烟煤和沥青焦浸润性的研究 姚桢1,2，刘卫1,2,3，陈毅1 （1.贵州师范大学 材料与建筑工程学院贵阳 550025；2.贵州省铝电解炭素材料工程技术研究中心贵阳 550025；3.贵州省教育厅无机非金属功能材料重点实验室贵阳550025） 摘要：以改质沥青为粘结剂电煅无烟煤和沥青焦为骨料，研究骨料粒度、加热温度、保温时间及振动次数对改质沥青浸润性的影响，并对不同粒度分布的电煅无烟煤和沥青焦的比表面积进行测定。结果表明，随着骨料粒度的减小，骨料颗粒的比表面积逐渐增大；改质沥青对电煅无烟煤和沥青焦的浸润性均随骨料粒度的减小和振动次数的增加而大幅度降低，随加热温度和保温时间的增加而逐渐增大。通过适当调整骨料粒度分布、加热温度、保温时间、振动次数等工艺参数，能够改善改质沥青对电煅无烟煤和沥青焦的浸润效果。 关键词：浸润性；改质沥青；电煅无烟煤；沥青焦；铝用炭素材料TQ533.3 文献标志码：A 文章编号：1007-7545（2017）09-0000-00 Study on Wettability of Modified Pitch on Calcined Anthracite Coal and Pitch Coke YAO Zhen1,2, LIU Wei1,2,3, CHEN Yi1 （1. College of Material and Civil Engineering, Guizhou Normal University, Guiyan 550025, China; 2. Guizhou Engineering Research Center for Carbon Materials of Aluminum Electrolysis, Guiyang 550025, China; 3. Guizhou Key Laboratory of Inorganic Nonmetal Function Materials, Guiyang 550025, China） Abstractffects of aggregate size, heating temperature, holding time, and vibration number on wettability of modified pitch were investigated with modified pitch as binder, calcined anthracite and pitch coke as aggregate. Specific surface area of calcined anthracite and pitch coke with different particle size distribution were measured by automatic surface area and porosity analyzer. The results indicate that specific surface area of aggregate particles rises with drop of aggregate size. Wettability of modified pitch on calcined anthracite and pitch coke is greatly reduced with drop of aggregate size and increase of vibration time, and rises with increase of heating temperature and holding time. It is possible to improve the wetting effect of modified pitch on calcined anthracite and pitch coke by appropriately adjusting aggregate size, heating temperature, holding time, and vibration number. Key words：wettability; modified pitch; calcined anthracite; pitch coke; carbon materials for aluminum electrolysis 铝用炭素材料作为铝电解工业的关键材料，通常采用炭质材料为骨料，具有良好粘结能力和高结焦值的煤沥青为粘结剂，经由骨料混合→粘结剂混捏→成型→焙烧等工艺制备而成，主要用于铝电解槽中电流的传递、参与电化学反应以及盛装高温铝液和电解质[1]。随着我国大型电