电气浮精滤电渗析深度处理油田污水试验研究应用昆虫学报.docVIP

电气浮-过滤-离子交换/电渗析组合工艺处理油田污水回用试验研究 张海薇1 李学凤2 张锡波2 许浩伟2 占程程2 1 中国地质大学（武汉）材料与化学学院 湖北武汉 430000 2 中石化胜利油田分公司孤岛采油厂，山东东营 257231 摘要：针对胜利油田部分区块污水富余与热采注汽需用清水的矛盾，提出了富余污水利用“电气浮-过滤-离子交换/电渗析”法深度处理后达到锅炉注汽用水替代注汽锅炉用清水的技术思路。通过现场试验、分析了各工艺处理前后的水质，结果表明，含油浓度降至 1 mg.L-1以下，出水可溶性固体含量降至 3500 mg.L-1以下， Ca2+和Mg2+的质量浓度降至 11 mg.L-1左右，达到锅炉注汽用水条件。处理后的水可以替代清水用于锅炉注汽，实现了污水资源化再利用，具有较好的经济及社会效益。 关键字：电气浮-过滤 电渗析 深度处理 污水 回用 Experimental Study of Electric floating-fine filtration-ion exchange/electrodialysis Combination process oilfield sewage reuse Zhang Hai-wei1 Li Xue-feng2 Zhang Xi-bo2 Xu Hao-we2i Zhan Cheng-cheng2 1 Faculty of Materials Science and Chemistry. Wuhan,Hubei 430000, China 2 Gudao Oil Production Factory，Shengli Oilfield Company. Sinopec. Dongying, Shandong 257231, China Abstract: For the contradiction between excess water and water for steam injection in part blocks of Shengli oilfield, a new method was provided, the electric floating-fine filtration- ion exchange /electrodialysis advanced treatment waste was used for boiler instead of clean water. Water quality before and after the process is analyzed through field test, the results showed that, the concentration of oil fell to 1 mg.L-1 below, the water soluble solid content dropped to 3500 mg.L-1 below, the mass concentration of Ca2+ and Mg2+ down to 11 mg.L-1, the quality of water conincided with the quality of steam injection boiler water. The sewage after treatment can replace clean water used for steam injection boiler, which has realized the reuse sewage recycle treatment and has good economic and social benefits. Keywords: Electric floating - fine filtration electrodialysis advanced treatment sewage reutilization 胜利油田部分区块进入特高含水期开发阶段以来，采出液液量大，生产开发过程中产生大量的富余污水需要无效回灌地层。目前，胜利油田某采油厂有污水回灌井62口，日污水回灌量2.9×104m3。回灌层的吸纳容量和选择难度越来越大，污水回灌处理难度加大，生产成本压力逐步增加。另一方面，该油田稠油热采产量比例高，占全厂产量的1/3多，稠油热采注汽锅炉用水均为清水，以汇入某联合站污水处理的 1#、9#站为例，两站注汽锅炉需求水量共计6000m3/d。 如何实现富余污水深度处理后资源化再利用，是近年来油田长效、环保一直探索的问题[1]。如果能够很好地解决污水替代清水注蒸汽的问题，对油田节能增效和可持续发展具有重要意义。 1 试验部分 1.1 试验用水 试