DNA的导电性Conductance.PPTVIP

BioMolecular Devices 奈米電子學 劉致為教授 環工所碩二 黃國威 self-organized bio-moleculardevices 簡單的介紹自我組合材料（self-assembled solid-state biomolecular materials）在電子元件的應用。 兩種不同的方法：top-down和bottom-up Biomolecular electronics (BME)的優點： 便宜（cheap）、容易製造（easy-to-fabricate）、自我組合、自我修復（self-repairing） self-organized bio-moleculardevices之特別電子傳導現象 charge transfer in proteins hopping and/or band-like transport (–) ligands can be engineered in a very .exible way, DNA have be found to be conductive, non-conductive or rectifying. Top-down approachself-assembled guanosine crystals (SAGC) SAGC SAGC的 I-V圖 右上：gap=60nm 左上：gap=120nm 左下：gap=800nm All the current–voltage (I–V) characteristics weremeasured at room temperature in the dark.120nm的圖約在+/-2V的地方有current出現，似MSM device BOTTOM-UP approach Metalloprotein = Azurin 2 cysteine groups 12 amino groupscontact，Ti the realization of molecular switches whose conduction state can be controlled by tuning their redox state with the help of an external voltage source (gate). Azurin的I –V圖 DNA的導電性（Conductance） 量測法： 結果：Nonlinear current-voltage curves are observed at ambient conditions as well as in vacuum and at cryogenic temperatures, (see the inset of the following figure). Typically, a gap of a few volts is observed. The voltage dependence of the differential conductance exhibits a peak structure (figure below), indicating that transport of charge carriers is mediated by the molecular energy bands of DNA DNA的導電性（Conductance） Electrostatic trapping of single conducting nanoparticles between nanoelectrodes 量測benzene ring的current-voltage characteristics  中間的為苯環 外接兩個硫原子 最外是金gold 若有a third terminal to the benzene molecule可以控制苯環的電流嗎？ 量測benzene ring的current-voltage characteristics Experimental current-voltage characteristic of a benzene-1,4-dithiolate molecule as measured by Reed, et al. (top). Two theoretical curves corresponding to the benzene molecule attached directly to flat electrodes (middle) to single gold atoms protr