乙醇火焰中生长一维碳纳米材料的研究进展_图文_百度文库.DOCVIP

第21卷第9期 Vol.21 No.9 中国有色金属学报 2011年9月 The Chinese Journal of Nonferrous Metals Sep. 2011 文章编号：1004-0609(2011)09-2119-07 乙醇火焰中生长一维碳纳米材料的研究进展 祁 祥1, 2, 4，张 峻1，张豫鹏1，潘春旭1, 3，钟建新2, 4 (1. 武汉大学 物理科学与技术中心，武汉 430072； 2. 湘潭大学 材料与光电物理学院，湘潭 411105； 3. 武汉大学 教育部人工微纳结构重点实验室，武汉 430072； 4. 湘潭大学 量子工程与微纳能源技术湖南省普通高等学校重点实验室，湘潭 411105) 摘 要：综述乙醇火焰中生长碳纳米管和碳纳米纤维等一维碳纳米材料的方法，及其微观结构、生长机理和物理化学性能。结合SEM和TEM等表征手段，重点述评了一维碳纳米材料的阵列控制生长和纳米同质异构结的制备。结果表明：乙醇火焰是制备碳纳米管和碳纳米纤维的有效方法，具有燃料储存安全和燃烧设备简单等特点。展望了乙醇火焰中生长一维碳纳米材料的发展趋势，并认为其特殊的微结构特征和奇异的物理化学性能以及在微纳米器件上的应用开发将是未来一段时间的研究热点。 关键词：碳纳米管；碳纳米纤维；火焰；乙醇；研究进展 中图分类号：TB303 文献标志码：A Progress of one-dimensional carbon nanomaterials synthesized from ethanol flames QI Xiang1, 2, 4, ZHANG Jun1, ZHANG Yu-peng1, PAN Chun-xu1, 3, ZHONG Jian-xin2, 4 (1. Department of Physics, Wuhan University, Wuhan 430072, China; 2. Faculty of Materials, Optoelectronics and Physics, Xiangtan University, Xiangtan 411105, China; 3. Key Laboratory of Artificial Micro- and Nano-structures, Ministry of Education, Wuhan University, Wuhan 430072, China; 4. Key Laboratory of Quantum Engineering and Micro-Nano Energy Technology, Department of Education of Hunan Province, Xiangtan University, Xiangtan 411105, China) Abstract: The synthesized methods, growth mechanism, microstructures and physical-chemical properties of one-dimensional carbon nanomaterials (1D-CNMs), including carbon nanotubes and carbon nanofibers, prepared from ethanol flame were reviewed. With the characterization of SEM and TEM images, the well-alignment and nanoscale homojunctions of 1D-CNMs were also reviewed. The results show that the ethanol flame is an efficient process for synthesizing carbon nanotubes and carbon nanofibers, because of its safe fuel storage and simple combustion equipment. It is considered that the future research of 1D-CNMs should be focused on their special microstructures, performances and device building. Key words: carbon nanotubes; carbon nanofibers; flames; ethanol; research progress 基金项目：国家自然科学基金青年项目(5100212