赵东元文章cm800489e.pdfVIP

3778 Chem. Mater. 2008, 20, 3778–3784 Ordered Mesostructured Rare-Earth Fluoride Nanowire Arrays with Upconversion Fluorescence Fan Zhang,† Ying Wan,‡ Yifeng Shi,† Bo Tu,† and Dongyuan Zhao*,† Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Inno VatiVe Materials, and Laboratory of Ad Vanced Materials, Fudan UniVersity, Shanghai 200433, People’s Republic of China, and Department of Chemistry, Shanghai Normal Uni Versity, Shanghai 200234, People’s Republic of China Recei Ved February 19, 2008. ReVised Manuscript ReceiVed April 5, 2008 Ordered mesostructured LaF3 nanoarrays have been, for the first time, synthesized via a one-step nanocasting process using La(CF COO) as a precursor and mesoporous silica as a hard template. The 3 3 characterization of SAXS and XRD patterns and TEM and SEM images shows that the LaF3 nanowire arrays have long-range regularity of hexagonal mesostructure (p 6mm) and single-crystalline feature. N - 2 sorption isotherms reveal that ordered mesoporous LaF3 products have high BET specific surface area (∼75 m2 3 /g), large pore volume (0.15 cm /g), and narrow pore-size distribution (the mean value of 4.3 nm). The upconversion fluorescence has been realized in the Yb3+/Er3+ (red/green) and Yb3+/Tm3+ (blue) codoped LaF3 nano