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Angewandte Chemie DOI: 10.1002/anie.201205333 Polymeric Heterojunction A Facile Band Alignment of Polymeric Carbon Nitride Semiconductors to Construct Isotype Heterojunctions** Jinshui Zhang, Mingwen Zhang, Rui-Qing Sun, and Xinchen Wang* Visible light photocatalysis has attracted great interest, water splitting.[8–10] The creation of tight junctions between offering a sustainable pathway to drive chemical reactions, two semiconductors not only depends on the electronic such as water splitting and carbon fixation.[1] In principle, structure of the semiconductors but also on other material heterogeneous photocatalysis involves the generation, migra- properties, such as electron affinity and work function.[6] tion, and separation of charge carriers in light-excited semi- Several kinds of photocatalytic heterojunctions have been conductors, in which the adsorbed substrates undergo redox developed by coupling different types of photocatalysts. For reactions with the separated electrons and holes.[2] The example, the combination of p-type and n-type semiconduc- photocatalytic performance has been reported to depend on tors has been reported to create anisotype p–n photocatalytic the intrinsic physicochemical properties of semiconductors, diodes, such as p-GaP/n-TiO ,[8a] p-NiO/n-TiO ,[8b] and p-