山西大同小峪煤矿煤系粘土岩夹矸地球化学特征-煤田地质与勘探.PDFVIP

第39 卷 第6 期 煤田地质与勘探 Vol. 39 No.6 2011 年 12 月 COAL GEOLOGY EXPLORATION Dec. 2011 文章编号: 1001-1986(2011)06-0006-05 山西大同小峪煤矿煤系粘土岩夹矸地球化学特征 王水利，梁绍暹 (西安科技大学地质与环境学院，陕西 西安 710054) : 采用化学法和中子活化(INAA)法，对山西大同小峪煤矿山西组和太原组的 3 件不同粘土岩 样品的 8 种常量元素(氧化物)和33 种微量元素含量进行了测定。通过对具有示踪意义的元素及其 比值的对比分析表明，3 个样品总体上均不具有典型的沉积岩特征，应该是由酸性或酸性偏碱性 火山物质(降落的或陆源搬运的)在地表覆水较浅的弱氧化条件下经原地淋滤、蚀变形成的。岩石总 体蚀变程度较高，不稳定或较不稳定的元素大量流失，甚至一些较稳定的元素(如高岭岩中的铁、 锰)也明显流失。蚀变环境及介质条件、成岩原始物质组成及其粒度大小以及粘土物质组成是造成 粘土岩类型及其不同类型间元素含量差异的主要原因。 ：煤系；粘土岩；地球化学；示踪；大同小峪煤矿 ：P619.232 ；P595 ：A DOI: 10.3969/j.issn.1001-1986.2011.06.002 Geochemical characteristics of clay parting from Xiaoyu coal mine of Datong, Shanxi WANG Shuili, LIANG Shaoxian (1. Collage of Geology and Environment, Xi ′an University of Science and Technology, Xi ′an 710054, China) Abstract: The contents of the major and trace elements in 3 samples of the claystone with different types and tex- tures, from the coal measures of the Taiyuan and Shanxi Formations of Permo-Carboniferous of Xiaoyu coal mine of Datong, Shanxi province, are detected by the methods of chemical analysis and INAA respectively. By the con- trast analysis of the elements with geochemical tracer and their ratio, three samples, on geochemistry as a whole, are not of the typical characteristics of sedimentogenic mudstone, and could be formed in situ from the alteration of acidic or alkali-acidic ash (fallout or water-carried) under the conditions of the shallower water and weak oxydation on the surface. The alteration of the claystone is stronger on the whole, and it causes much loss of the unstable elements, even some of more stable elements,