物理化学试题4（Physical chemistry questions 4）.docVIP

物理化学试题4（Physical chemistry questions 4） Physical chemistry and colloid chemistry simulation questions First, the choice of questions (individual, 1.5 points per subject, a total of 30 points) 1., about enthalpy, the following statement is incorrect A. H=Q is suitable for closed system only work process for B. isobaric condensation under atmospheric pressure, the process of H is U C for Delta U+W Delta H= D. of any system only on the isobaric volume of an ideal gas at constant volume of delta H= Delta U+V Delta P 2. which of the following equations and Raouls Law (independent) A. PA=PA*xB B.P=PB*+ (PB*-PA*) xB C. B= B* (T, P) +RTlnxB D. B= B0 (T, P) +RTlnCB/C0 3. the ideal gas reaction of A (g) +3B (g) 2C (g) rGm delta theta =-3.0kJ.mol-1, reaction C (g), A (g) + B (g), Kp theta at 400K is () A. 2.46, B. 0.64, C. 1, D. 1.57 4. will be a ideal gas temperature from T1 to T2 if the change of heating, non constant volume method, the variation of U values of thermodynamic energy should be what value? () A. U = 0 B. U = Cv (T2-T1) C. U D. U are not equal to other values 5. at constant temperature and constant pressure, when the chemical reaction reaches equilibrium, there will be () A. B. C. D. 6.n mol an ideal gas at a constant volume under heating by T1 to T2, its entropy for a given S1, the same amount of gas at constant pressure heating by T1 to T2, the change of entropy for Delta S2, Delta S1 and delta S2 is the () A. S1 S2 B. S1 = Delta Delta Delta Delta S2 C. S1 S2 D. S1 = Delta Delta Delta S2 = 0 When 7.298K, the osmotic pressure of 0.01mol/kg sugar is pi 1, and the osmotic pressure of 0.01mol/kg salt water is pi 2, then the relation between PI 1 and PI 2 is () A., PI, 1, PI, 2, B., PI, 1, PI, 2, C., PI 1 = Pi 2, D., indefinite relation 8. it is known that the lowest azeotropic mixture formed from ethanol and water contains 4.43% water. Liquor produced in a distillery contains 35% ethanol, which is separated and purified by fractionation A. pure water and pure et