精脱硫（Fine desulfurization）.docVIP

精脱硫（Fine desulfurization） In recent years, with the steel industrys huge demand for coke and high The rapid development of coking industry, the expansion of coke production capacity, disorderly production Substantial growth at the same time, the by-product of a large number of coke oven gas has led to coke The environment in the carbon producing areas has deteriorated sharply, and many independent coking processes have been adopted Enterprises only focus not change, a large number of coking residual coke oven gas to take Some lanterns burning is emptying, serious pollution of the environment, but also cause resources Waste。 As oil and gas shortage of the energy needs of the country, fully and rationally The use of a large number of point lanterns efflux of coke oven gas, construction of the resources section of the source To achieve sustainable economic development is of great significance. 1 utilization of coke oven gas Composition and impurity content of coke oven gas The main components of coke oven gas are H2, CO, CH4, CO2 and so on, With the difference of coking proportion and operation process parameters Composition varies slightly. The composition of general coke oven gas is shown in Table 1, impurities Contents are shown in table 2. . Process technology for making methanol from 2 coke oven gas 2.1 basic process of methanol production from coke oven gas Since the end of 2004, the worlds first 8 * 104t/a coke oven Since the project of gas methanol production was completed and put into operation in Yunnan, Qujing, Nearly 10 sets of coke oven gas methanol plants have been put into commercial operation, The design of the single set of equipment is mostly (10~20) * 104t/a, its basic The process is shown in figure 1. First, the coke oven gas from the coking plant is sent Into the storage tank buffer, compression, compression, followed by hydrogenation of refined sperm The total sulfur desulfurization, the volume fraction is less than 0.1 * 10-6, the coke oven coal