无机阴离子调整剂对蓝晶石矿物浮选行为及溶液化学研究探究.docVIP

无机阴离子调整剂对蓝晶石矿物浮选行为摘要：通过蓝晶石、石英及黑云母的浮选试验，研究了对矿物浮选行为的影响。结果表明NaF与十二胺添加顺序的不同对石英黑云母种矿物的浮选基本没有影响Na2SiO3与十二胺的添加顺序不同对黑云母的影响较小，对蓝晶石起到强的抑制作用，且Na2SiO3在十二胺之后添加对矿物的抑制作用更强(NaPO3)6的添加对蓝晶石及石英均起到较强的抑制作用，对黑云母的抑制较弱；Na2S除了对蓝晶石起到轻微的活化作用外，对石英及黑云母两种矿物的浮选基本没有影响。Na2SiO3、Na2S、(NaPO3)6对蓝晶石、石英及黑云母矿物的抑制或活化作用的机理。 关键词：；蓝晶石；石英；黑云母；浮选；溶液化学 of Inorganic Anion Regulators on Floatability of Kyanite Minerals and Solution Chemistry Abstract: The influences of inorganic anion regulators on the flotation of kyanite, quartz and biotite by flotation experiments. The results show that laurylamine was used as collector, the addition and the orders of NaF had no effect to the quartz and biotite minerals floatation, but had active function on kyanite. The addition and the orders of Na2SiO3 had little effect to the biotite. The kyanite mineral was inhibited by Na2SiO3, and the actions were strengthened when the reagents were added after collector. The addition of (NaPO3)6 had strong inhibition effect to the quartz and kyanite minerals floatation, but had weaker inhibition function on biotite. The addition of Na2S no effect to the quartz and biotite minerals floatation, but had slight activate effect on kyanite. According to calculation of?flotation?solution chemistry, relationship between activation and inhibition mechanism of inorganic anion regulators were analyzed. Key words:?regulators, kyanite, quartz, biotite, flotation, solution chemistry, inhibition, activation 蓝晶石是一种耐火度高、高温体积膨胀大的天然耐火原料矿物，随着高附加值蓝晶石制品开发应用和市场对蓝晶石材料需求不断增加，蓝晶石的分选提纯技术得到企业和研究者的重视[1]。浮选是蓝晶石矿物选别的重要工艺，同时也是获得高品质蓝晶石精矿的主要手段，在国内外得到广泛应用[-4]。 , 一般是先添加无机阴离子调整剂后添加捕收剂，进而使矿物分离。但是有些文献资料表明, 捕收剂和调整剂的添加顺序不同, 将会对浮选产生不同的结果, 进而影响矿物分选的选择性[7-9]。 总之，在不同的浮选体系下对矿物的浮选作用不同，且作用的机理也比较复杂。为此，本论文作者研究了在十二胺浮选体系中多种对蓝晶石、石英和黑云母浮选行为影响规律，并分析其可能存在的活化或抑制作用机理。 1.实验 1.1纯矿物的制备 试样所用的蓝晶石、石英、黑云母矿样分别来自河北邢台、江苏东海地区以及河北灵寿。对矿物的制备过程都是采用手选富块，多段磨矿、筛分作业完成的，纯度分别为98.15%、99.80%和99.20%，粒度为为-0.105+0.043mm，满足试验要求。对制备好的纯矿物进行了化学成分分析，见表1。 表1 试验用纯矿物化学成分分析矿物名称 Al2O3 SiO2 Fe2O3 Na2O MgO K2O CaO P2O5 蓝晶石 61.93