疏水缔合型聚丙烯酰胺后水解工艺的正交试验研究-海洋石油.PDF

　 海　洋　石　油 　29 　 1 　OFFSHORE　OIL 　　　·67 · :1008-2336(2009)01-0067-05 1 2 2 2 1 1 王　鹤, 郭拥军,冯茹森, 孙怀宇,柳建新, 付　俊 (1., 610500; 2.·, 610500) 　:随着疏水缔合型聚丙烯酰胺作为一 驱油剂在油田的应用越来越广泛, 对其聚合物的要求不断提高。依据疏水 缔合型聚丙烯酰胺本身特殊的分子结构及其特殊的溶液结构, 设计了 一组针对疏水缔合型聚丙烯酰胺的后水解工艺的 正交试验, 试图通过后水解工艺各 个因素的调节, 来改善聚合物的溶解性、溶液黏度等参数, 从而可以更大的满足油田上 的要求。在综合考虑了聚合物的溶解性, 溶液的表观黏度和特性黏数的基础上, 通过正交试验来优选出水解剂 类、水 解温度、水解时间及加水量的工艺参数。结果表明, 最佳的后水解工艺条件为:水解剂为Na CO /NaOH 混合物, 水解时 2 3 间为3 h, 水解温度为90 ℃, 加水量为60 g。 :;;; :TE357.46　　　　:A An orthogonal test study of posthydrolysi s process of hydrophobic associative polyacrylamide Wang He,G o Yongj n, Feng R oshen, S n H aiy , Li Jianxin, F J n (1.The Graduate School of Southwest Petroleum University, Chengdu 610500;2.S tate Key Laboratory of Oil and Gas Reservoir Geology and E p loitation ·Southwest Petroleum University, Chendu 610500) Abstract:Hydrophobic associative polyacrylamide were sed as an oil displacement agent in oilfields, the req irements of its polymers w ere also improved.In this paper, based on special molec lar str ct re of the sol tion and its special str ct re, an orthogonal test of the posthydrolysis process of hydrophobic association polyacrylamide w as designed to reg late all factors of posthydrolysis process and improve the sol bility of polymer and viscosity of the sol tion w hich can meet the demands of the oilfields.Polymer sol bility, viscosity and intrinsic viscosity w ere taken into consideration and the types of hydrolytic agent, hydrolytic temperat re, hydrolytic time and the w ater q ality were selected based on orthogonal test.The res lts showed that the best conditions for the posthydrolysis process were:hydroly