导电碳修饰隔膜在高硫载量锂硫电池中的作用-储能科学与技术.PDFVIP

导电碳修饰隔膜在高硫载量锂硫电池中的作用 裴海娟，郭 瑞，李 永，刘 雯，陈珠君，王 勇，解晶莹 （空间电源技术国家重点实验室，上海空间电源研究所，上海200245 ） 摘 要：研究了分别以乙炔黑、科琴黑、Super P、气相生长碳纤维、石墨烯、碳纳米管、XE-2 为正极侧修饰层 2 的隔膜对高硫载量（5.4 mg/cm ）锂硫电池电性能的影响。XE-2 、Super P、石墨烯、科琴黑、气相生长碳纤维涂 覆隔膜有助于提高隔膜正极侧的保液能力和导电能力；石墨烯、Super P 涂层对多硫化锂有很好的阻挡、吸附作 用。涂覆石墨烯的隔膜装配的电池的首次放电比容量可达 1007 mA·h/g ，远远高于采用空白隔膜的电池（340 mA·h/g），循环100 次后放电比容量为539 mA·h/g，仍然高于采用空白隔膜的电池（399 mA·h/g）。 关键词：锂硫电池；隔膜；导电碳修饰；高硫载量 doi: 1012.028/j.issn.2095-4239.2017.0053 中图分类号：TM912.9 文献标志码：A 文章编号：2095-4239 （2017 ） 00-000-00 Conductive carbon-coated separator for high sulfur-loading lithium sulfur batteries PEI Haijuan, GUO Rui, LI Yong , LIU Wen, CHEN Zhujun, WANG Yong, XIE Jingying (State Key Laboratory of Space Power Technology, Shanghai Institute of Space Power-sources, Shanghai 200245, China) Abstract: The effects of separators consisting of cathode-side functional layers separately composed of acetylene black, ketjen black, Super P, vapor-grown carbon fiber, graphene, carbon nano-tube and XE-2, 2 on high sulfur-loading （5.4 mg/cm ）lithium sulfur batteries have been investigated. The separators coated by XE-2, Super P, graphene, ketjen black, vapor-grown carbon fiber can improve the electrolyte adsorbility and electrical conductivity of cathode side. Besides, the separators coated by Super P and graphene can obstruct and adsorb lithium polysulfide. The battery with separator coated by graphene · -1 delivers a specific capacity as high as 1007 mAh g , much higher than that of untreated separator (340 mA ·h/g). After 100 cycles, the battery with separat