多重激子产生及其在先进太阳电池中的应用.pdf

多重激子产生及其在先进太阳电池中的应用 Multiple Exciton Generation and Its Application in Adanced Solar Cell 1,2 2 苏未安 、沈文忠 1、江西理工大学理学院， 赣州341000 2. 上海交通大学太阳能研究所， 上海交通大学物理系凝聚态光谱与光电子物理实验室 上海200240 Loss Processes in a Standard Solar Cell The Shockley-Queisser detailed balance power conversion efficiency limit for a typical single-junction c -Si PV cell under the standard AM1.5 is 31% at 1.1eV. 69% of incident solar power does not converted to electrical power. ① Nonabsorption of below bandgap photons (~20%) ② Lattice thermalization loss (~40%): converted to heat through phonon emission by inelastic scattering of hot electrons and holes with the crystal lattice ③ Junction loss ④ Contact voltage loss ⑤ Recombination loss (~2%, unavoidable) The employment of below bandgap photons and prevention of hot carrier cooling via phonon emission may ultimately yield meaningful efficiency gains for solar photon conversion. MEG: Nanotechnology for Next PV Milestone Absorption of a single photon produces a single exciton, the photon excess energy is dissipated as heat via phonon emission QE of photon-to-exciton conversion is zero below Eg, and is 100% above it Shockley-Queisser “ultimate” limit shows a maximum of 44% at an Eg of 1.1eV The number of excitons produced by a