氮氧自由基—过渡（稀土）金属离子配合物的结构与性质研究.pdfVIP

NITPhOn-Pr( )NITPhNEt ()IR 2 UVESR : [Mn (hfac) (NITPhOn-Pr) ]·NITPhOn-Pr(1)Co(hfac) (NITPhOn-Pr) (2)Ni(hfac) 2 4 2 2 2 2 (NITPhOn-Pr) (3) Dy(hfac) (NITPhOn-Pr) (4) Tb(hfac) (NITPhOn-Pr) (5) 2 3 2 3 2 Sm(hfac) (NITPhOn-Pr) (6)Mn (hfac) (NITPhNEt ) (7)hfac 3 2 2 4 2 2 X- RE(hfac) (NITPhOn-Pr) (RE=DyTb 3 2 Sm) Co(hfac) (NITPhOn-Pr) Ni(hfac) (NITPhOn-Pr) 2 2 2 2 Mn Mn (hfac) (NITPhNEt ) 2 4 2 2 [Mn (hfac) (NITPhOn-Pr) ]·NITPhOn-Pr 2 4 2 [Mn (hfac) (NIT PhOn-Pr) ]·NITPhOn-Pr 2 4 2 TG/DSC (4)(6) (4)(5)(6)(1) (DSC) Dy(hfac) (NITPhOn-Pr) (4) 3 2 Tb(hfac) (NITPhOn-Pr) (5) Sm(hfac) (NITPhOn-Pr) (6) [Mn (hfac) (NITPhOn- 3 2 3 2 2 4 Pr) ]·NITPhOn-Pr(1) 2 (298.15K) III Abstract Two new Nitronyl nitroxide Radicals ligand (2-(4-p-propoxy)-4,4,5,5-terameth ylimidazoline-1-oxyl-3-oxide(NITPhOn-Pr), 2-(4-diethylin)-4,4,5,5-teramethylimidaz oline-1-oxyl-3-oxide(NITPhNEt ) have been synthesized