电泳漆pH对漆膜质量的影响.docxVIP

【涂装】电泳漆 pH 对漆膜质量的影响张亚刚（宝鸡华山工程车辆有限责任公司，陕西 宝鸡721013）摘要：以两起电泳底漆的生产质量事故为切入点，经初步分析 后以双组分阴极电泳涂料 pH 为研究对象，从漆膜表面质量、漆 膜厚度、光泽度、附着力、冲击强度等性能方面进行对比实验， 分析其对漆膜质量的影响，并分析了 H+在成膜过程中的作用机 理。实验结果表明，电泳漆 pH 较高时涂膜外观质量较好，在 pH 5.40 时，漆膜逐渐变粗糙，并随着 pH 的逐渐降低，漆膜 外观质量越来越差。漆膜厚度随电泳漆 pH 的降低呈先升高后下 降趋势，在 pH = 5.60 时，漆膜厚度达到最大。漆膜光泽与附着 力随着电泳漆 pH 的降低呈下降趋势。漆膜冲击强度和硬度受电 泳漆 pH 的影响不大。 关键词：阴极电泳漆；pH；返溶；电渗；附着力；漆膜厚度； 光泽度；冲击强度中图分类号：TQ639.8文献标志码：A 文章编号：1004 – 227X (2014) 14 – 0612 – 04Effect of pH of electrophoretic paint on its film quality// ZHANG Ya-gangAbstract: The effect of pH of a two-component cathodic electrophoretic paint on properties of the coating obtained therefrom was studied in view of two quality accidents in construction of electrophoretic primer. A series of properties (including surface quality, thickness, glossiness, adhesion strength, and impact strength) of the coating obtained at different pHs were tested and compared. The role of H+ in the film-forming process was analyzed. The results indicated that the higher the pH is, the better the appearance of coating is. The coating obtained at pH 5.40 becomes rough, and the decreasing of pH increases the roughness and decreases the appearance quality. The thickness of coating is increased initially and then decreased with the decreasing of pH, reaching the maximum at pH = 5.60. The glossiness and adhesion strength are decreased with the decreasing of pH. The impact strength and hardness are affected slightly by pH.Keywords: cathodic electrophoretic paint; pH; redissolution;electrodialysis; adhesion; coating thickness; glossiness; impact strength收稿日期：2014–03–06修回日期：2014–04–09 作者简介：张亚刚（1985–），男，陕西宝鸡人，助理工程师，主要从事汽车涂装研究。作者联系方式：(E-mamailto:yagang1985@il) yagang1985@。Author’s address: Huashan Engineering Vehicle Co., Ltd.,Baoji 721013, China电泳涂装将导电性的被涂物浸渍在水性涂料中， 在两极间通直流电，在被涂物表面上形成一层均一、 致密、不溶于水的涂膜，是一种低污染、省能源、省 资源的涂装方法。电泳涂膜具有涂膜平整，耐水性和 耐化学性好等优点，其工艺容易实现涂装工业的机械 化和自动化，适合形状复杂，有边棱角、孔穴工件的 涂装。阴极电泳是目前国内外应用最广的涂装技术， 因具有高效、优质、安全、经济等优点而被广泛应用 于汽车、建材、家电等工业领域[1]。双组分阴极电泳涂料通常