六亚甲基四胺辅助微波水热法合成γ-MnS微晶球及-IngentaConnect.PDF

40 12 1779 40 12 Vol. 40 No. 12 2 0 1 2 1 2 JOURNAL OF THE CHINESE CERAMIC SOCIETY December 2012 γ-MnS ( 710021) (HMTA)γ-MnS X HMTA 5 mmol HMTA HMTA 2 μm– γ-MnS 300400 nm HMTA γ- O782 A 0454–5648(2012)12–1779–07 2012–11–29 10:09:55 /kcms/detail/11.2310.TQ1009.201212.1779_022.html Hexamethylene Tetramine-Assisted Microwave Hydrothermal Synthesis and Optical Properties of Spherical γ-MnS Crystallites XIN Yu HUANG Jianfeng CAO LiyunLIU Jia WU Jianpeng (Key Laboratory of Auxiliary Chemistry Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science Technology, Xi′an 710021, China) Abstract: Spherical γ-MnS crystallites were synthesized with manganese chloride and thioacetamide as source materials and hexa- methylene tetramine (HMTA) as an additive by a microwave hydrothermal process. The influence of the HMTA amount on the phase structure and morphology of the crystallites was investigated by X-ray diffraction and field emission scanning electron microscopy, respectively. The results show that the morphology of the products changes from hexagonal columns to hexagonal flakes and self-assembled into spherical crystallites when adding the HMTA of 5 mmol. The surface of the self-assembled spheres becomes smoother, and the corresponding particle size decreases and the particle size distribution becomes narrower when the amount of HMTA increases. The UV–Visible spectrum analysis indicates that the hexagonal flakes self-assembled spherical γ-MnS crystallites have an intensive ab