再碱化钢筋-砂浆试件再碳化后的电化学性能研究-同济大学学报.DOC

文章编号：0253-374X(2012)07- DOI: 3969/j.issn.0253-374x.2012.07.000 再碱化钢筋-砂浆试件再碳化后的电化学性能 王昆1,2屈文俊1，张俊喜3, 李沛豪4 （同济大学　土木工程学院，上海200092；2.江苏科技大学　土木与建筑工程学院，江苏　镇江，212003；3.上海电力学院　能源与环境工程学院，上海　200090；4. 浙江工业大学建筑工程学院。,310014）  摘要：为模拟再碱化钢筋混凝土结构的耐久性，对再碱化后的钢筋-砂浆试件进行加速碳化试验，碳化的时间采用试件进行再碱化前第1次碳化所用的时间。采用交流阻抗谱、极化曲线和pH测试等测试方法研究再碳化过程中钢筋电化学和水泥砂浆碱性的变化。试验结果表明：在本试验条件下，再碳化后，试件的pH值仍然大于10；再碳化后，钢筋的腐蚀电流虽然有所增大，但仍小于再碱化前的腐蚀电流密度，钢筋的腐蚀电位负移，但仍大于再碱化前的腐蚀电位。研究结果表明，再碱化后的混凝土结构对CO2具有较好的抵抗侵蚀的作用。 关键词：再碱化；再碳化；砂浆；钢筋锈蚀 中图分类号：TU375 文献标识码：A The electrochemical study on realkalisated steel-mortar after re-carbonation WANG Kun1,2，QU Wenjun1，ZHANG Junxi3, LI Peihao4 College of Civil Engineering, Tongji University, Shanghai 200092, China；of Civil Engineering and Architecture, Jiangsu University of Science and Technology，Zhenjiang 212003，China;3.Institute of Engergy and Enviroment Engineering, Shanghai University of Electric Power, Shanghai　200090, China; 4 College of Civil Engineering and Architecture, Zhejiang University of Technology, Hangzhou 310014, China） Abstract: A re-carbonation test of realkalisated steel-mortar was carried out for the simulation on the durability of realkalisated reinforced concrete. The re-carbonation time was the same as the first carbonation time before realkalisation. The electrochemistry of steel and the alkaline of the cement mortar was studied with electrochemical impedance spectroscopy (EIS), polarization curve and the measurement of pH. The test results show that under the experimental conditions, the pH of cement mortar is above 10 after re-carbonation; after re-carbonation, the corrosion current density of steel increases and is less than before realkalisation; the corrosion potential of steel decreases, but is more than before realkalisation. Key words: realkalisation, re-carbonation, mortar; steel corrosion 在一般大气环境下，混凝土结构会受到CO2的侵蚀作用，使孔溶液中的含量逐渐减少，值逐渐下降。当值下降到11.5左右时，钝化膜不再稳定当值降至9～10时，钝化膜的作用完全被破坏，钢筋处于脱钝状态，锈蚀就有条件发生了。由于部分碳化区的存在，钢