纳米SiO_2改性对降低聚丙烯薄膜溶剂残留性能的影响研究.pdf

摘 要 随着我国对食品安全方面的关注越来越大，重视程度越来越高，人们对食品 包装材料的要求也越来越高，减少食品软包装材料中的溶剂残留的研究逐渐成为 科研的热点。聚丙烯薄膜作为一种广泛应用的食品包装材料，兼具良好的耐低温 性、高挺度、高耐热性、耐腐蚀和卓越的光学性能。本课题主要通过在聚丙烯树 脂中加入纳米SiO2 改性剂的方法，来制备聚丙烯复合材料，在确保或者提高其热 力学性能、阻隔性能和印刷性能前提下，提高聚丙烯的结晶度，即通过减少薄膜 中聚丙烯分子链间的自由体积来减少油墨中有机溶剂在食品包装材料上的残留 以及迁移，从而达到降低薄膜中溶剂残留的目的。前期研究表明此方法具有可行 性，同时这也是本论文的创新点，具有很高的科研价值。 本研究制备了纳米SiO2 添加量分别为0.00%，0.02%，0.03%，0.06%和0.09% 的改性聚丙烯薄膜，并对其微观结构、热力学性能、阻隔性能、印刷性能、自由 体积和溶剂残留做了测试研究。 研究结果表明：经过纳米 SiO 改性后，聚丙烯薄膜的晶粒尺寸减小，结晶 2 度提高。同时，对薄膜的自由体积以及溶剂残留做了深入细致的实验和分析，发 现纳米SiO 改性剂的加入，能够有效的降低聚丙烯薄膜的自由体积，从而降低有 2 机溶剂在薄膜表面的吸附和扩散，达到降低溶剂残留的目的。 关键词: 聚丙烯；纳米 SiO ；结晶度；自由体积；溶剂残留 2 Abstract Research about reducing residual solvent of food flexible packaging has recently become a hot spot with more and more attention and requirement on food security. Polypropylene membrane, as a widely used food packaging material, has the function of low temperature resistant, high stiffness, high heat resistance, corrosion resistance and excellent optical property. Polypropylene membrane was modified by nano-silica in this paper, to obtain a new composites material and improve its crystallinity on the premise of keeping polypropylene membrane’s thermodynamic properties, barrier properties, printability. The free volume between molecular chains could be decreased and the solvent from printing ink could hardly residue and migrate on the surface of modified polypropylene membrane. As a result, we can achieve ours purpose of reducing residual solvent. This was the innovation of this paper and previous studies have shown that this method is entirely feasible with high scientific value. Modified polypropylene memb