钯催化剂用于除去氢气中氧气的试验研究.PDF

钯催化剂用于除去氢气中氧气的实验研究 朱冬生，曾力丁，谢振 华南理工大学传热强化与过程节能教育部重点实验室 （广州市五山路381号华南理工大学化工与能源学院，510640） 摘要：以活性氧化铝为载体，采用超声波浸渍法制备一系列不同钯含量的纳米催 化剂，将此催化剂用于除去氢气中的微量氧气的实验。实验测定了在一定的入口 氧气浓度下，钯含量，氢气空速对出口氧气浓度的影响，采用红外线热成像仪检 -1 测催化反应床层的区域。实验表明，在操作空速范围（4～10s ）内，当钯含量 低于 0.15％时，反应速率受扩散和反应速率两步骤共同控制；钯含量高于 0.2 ％时，反应主要受外扩散控制，增大钯含量对出口氧浓度影响很小。 关键词：钯催化剂，氢气，氧气，空速，扩散 中图分类号：TQ016 The experimental investigation of elimination of O in hydrogen 2 under the catalyzing of palladium Abstract: A series of nanosised palladium catalysts with different content of palladium supported by γ-Al O were prepeared by ultrasonic impregnation method. 2 3 The catalysts were used to the experiment of elimination O2 in hydrogen. The concentration of O2 after reaction was measured to evaluate the influence of content of palladium and the space velocity of H2 . The result of experiment shows that in the -1 operational range (4 ～10s ) of space velocity of H , the reaction rate is controlled by 2 both the process of diffusion and reaction when the content of palladium is less than 0.15%. The reaction rate is controlled mainly by the process of reaction when the content of palladium is more than 0.2%; it’s no more effective for the elimination of O2 to improve the content of palladium. Key Words: palladium catalyst, hydrogen, oxygen, space velocity, diffusion 基金项目：教育部新世纪优秀人才支持计划 NCET040826, 高等学校博士点专项科研基金 前言 大型汽轮发电机组一般采用氢气作为冷却介质。用氢气作为冷却介质具有 散热效果好、通风阻力小、不腐蚀设备等优点，但在实际应用过程中，存在氢气 湿度过高，受到密封油污染、含有氧气影响安全运行等问题。用含有水、油、氧 等杂质较多的氢气去冷却发电机组，不但对发