板材甲醛释放试验及其释放参数的测定.pdfVIP

中国环境科学 2014,34(2) ：532~538 China Environmental Science 板材甲醛释放实验及其释放参数的测定 * 池 东,李立清 ,马卫武 ( 中南大学能源科学与工程学院,湖南 长沙 410083) 3 摘要：采用 1m 的小型环境模拟舱,测试了不同温度和装载度条件下胶合板、密度板、细木工板和复合地板中甲醛释放规律.研究发现: 甲 醛浓度在初始阶段(0~3h)均迅速增大,随后速度慢慢减小,最后浓度趋于恒定值;温度升高会促进板材内甲醛释放,温度每升高 5 ℃ , 甲醛释放 量会增加 10%~30%;而装载度增大则会减少单位体积板材内甲醛的释放量.利用不同装载度条件下板材在密闭环境舱散发过程和平衡状态 浓度,求解了影响板材释放特性的关键释放参数:可散发初始浓度 Cm,0 、扩散系数 Dm 和分配系数 K ;模拟计算的浓度结果与实验测试数据吻 合良好,为研究板材甲醛释放规律提供了一种有效手段. 关键词： 甲醛释放；人造板；释放参数；密闭环境舱 中图分类号：X131 文献标识码：A 文章编号：1000-6923(2014)02-0532-07 Experience research on formaldehyde emission from wood-based panels and measurement of emission parameters. CHI Dong, LI Li-qing∗, MA Wei-wu (School of Energy Science and Engineering, Central South University, Changsha 410083, China). China Environmental Science, 2014,34(2) ：532~538 Abstract ：The measurements of formaldehyde emission from plywood, density board, block board and laminate flooring were obtained using a 1m3 small environment chamber at different temperatures and loading degrees. The experimental results showed that quick emission of formaldehyde occurred initially (0~3h), and then tended to decrease over time. Higher temperatures facilitated formaldehyde emission from wood-based panels, the total emission increased 10%~30% with a temperature increase of 5 ℃, while the formaldehyde emissions from unit volume panel decreased at higher loading degrees. The key parameters: the initial mobile concentration, Cm,0, the diffusion coefficient, Dm and the partition coefficient, K, determining formaldehyde emission from wood-based panels, were calculated by using emission process and equilibrium concentration in the closed environment chamber at a series of load degrees. The simulation results were coincident with experimental data, which indicated that the method used in