干法水泥回转窑共处置滴滴涕废物的示范工程.PDFVIP

中国环境科学 2012,32(7) ：1326~1331 China Environmental Science 干法水泥回转窑共处置滴滴涕废物的示范工程 * 彭 政 ,余立风,丁 琼,王开祥,高新华 (环境保护部环境保护对外合作中心,北京 100035) 摘要：利用新型干法悬浮预热预分解回转窑对滴滴涕废物进行共处置研究.滴滴涕废物以 1t/h 的投加速率,从窑尾烟室加入窑系统, 比较了 未处置废物工况和处置滴滴涕废物工况下烟气、生料、熟料、飞灰中滴滴涕和二 浓度.结果表明:在投加滴滴涕废物工况下,滴滴涕得 到有效分解,其销毁率和销毁去除率分别为 99.99953%和 99.999982%;在处置滴滴涕废物前后烟气二 浓度没有发生明显变化,其浓度排 放远低于水泥窑废物处置要求低于 0.1ng-ITEQ/Nm3 的水平;该水泥生产工艺系统在处置滴滴涕废物时,二 烟气排放因子为 0.0396µg/t 熟料,熟料排放因子为 0.220µg/t;滴滴涕废物处置对炉窑生产,运行工况参数和常规污染排放没有显著影响. 关键词：干法水泥回转窑；滴滴涕；二 ；共处置；排放因子 中图分类号：X705 文献标识码：A 文章编号：1000-6923(2012)07-1326-06 Demonstration study of co-processing of DDT in a preheater/precalciner cement kiln system. PENG Zheng *, YU Li-feng, DING Qiong, WANG Kai-xiang, GAO Xin-hua(Foreign Economic Cooperation Office, Ministry of Environmental Protection, Beijing 100035, China). China Environmental Science, 2012,32(7)：1326~1331 Abstract ：Co-processing of DDT[2,2-bis(4-chlorophenyl)-1,1,1-trichloroethane] via a modern preheater/precalciner kiln system was characterized. DDT contained waste was fed at the inlet of transition chamber with feeding rate of 1 t/h. Concentration of DDT and PCDD/Fs of flue gas in main stack under co-processing and blank operation was measured. Additionally, the raw meal, clinker and bag filter fly ash during the co-processing operation were sampled for analysis of DDT and PCDD/Fs. The destruction efficiency (DE), destruction and removal efficiency (DRE) for DDT were 99.99953% and 99.999982%, respectively, suggesting DDT was effectively destructed. The average PCDD/Fs concentration of flue gas was 0.014ng TEQ/Nm3 3 , which was greatly lower than the national limit of 0.1ng-ITEQ/Nm , furthermore, there was no sign