一种高折光指数聚合物透明树脂的合成似与性质.pdfVIP

46 3 ( ) Vo.l 46 No. 3 2008 5 JOURNAL OF JILIN UNIVERS ITY ( SCIENCE ED ITION ) M ay 2008 2 , , , ( . , 300 2; 2. , 066000) : 将具有高折光指数的硫和苯环等基团引入含 C C化合物的分子结构中制备了单 甲 基丙烯酸苯硫酚酯( PTMA ), 并利用 FT IR, H NMR 和HPLC 等技术对其结构进行表征. 将 PTMA 作为单 与苯乙烯进行共聚, 制备得到含硫透明光学树脂. 对其性能测试结果表明, 共聚树脂具有较高的可见光透光率, 而且随着 PTMA质量分数的增加, 树脂的折光指数和密 度线性增大, 冲击强度提高. : 光学树脂; 折光指数; 透明性 : O633. 3 : A : 67 -5489( 2008) 03-0539-04 Synthesis and Properties of Polymer TransparentResins with High Refractive Index 2 Y IN Jiu-mei, CHEN X i-hong , ZHAO Deng-feng, L IN Quan ( . K ey Lab of Supram olecular S tructure andM aterials, College of Chem istry, Jilin University, Changchun 300 2, China; 2. olaite Qinglun Company, Qinhuangdao 066000, H ebeiProvince, China) Ab stract: Benzene ring and sulphur groupsw ere introduced into a compound contain ing C C double bonds to prepare a novelmonom er S-phenylthio-methacrylate ( PTMA ), the structure of wh ich w as characterized by H NMR, FT IR and HPLC. The new k inds of transparent polym eric resins w ere obtained through the copolym erization of PTMA and styrene. The copolym er resins possessed h igh refractive indexesw ith a good transparency. W ith the content ofPTMA increasing, the refractive index of the copolym er resinw as enhanced, and the mi pact resistancew as mi proved. Key wo rds: optical resin; refractive index; transparency , [ ~ 3] . , , [ 4, 5] . [ 6, 7] , [ 8, 9] . , ( PTMA ), . PTMA , , . : 2007-09-29. : ( 969~ ), , , , , E-m ail: y