戊二醛交联胶原蛋白ΠPVA复合纤维的结构与性能.PDFVIP

第 28 卷 　第 11 期 纺 　织 　学 　报 Vol. 28 　No. 11 2007 年 11 月 Journal of Textile Research Nov. 　2007 ( ) 文章编号 2007 戊二醛交联胶原蛋白PVA 复合纤维的结构与性能 王雪娟 , 唐屹 , 吴炜誉 , 徐建军 , 叶光斗 ( 四川大学 高分子材料工程国家重点实验室 ,四川 成都 　610065) 摘 　要 　在胶原蛋白与 PVA 复合后的溶液中加入戊二醛交联剂 ,得到稳定的复合纺丝原液 ,再用湿法纺丝得到初 生纤维 ,经热拉伸和热定型、缩醛化处理得到胶原蛋白PVA 复合纤维。复合纤维的强度、模量、伸长率分别达到 3. 74 cNdtex 、44. 60 cNdtex 、31. 30 % ;结晶度为60. 79 % ;水中软化点和回潮率分别为105 ℃和8. 9 % 。通过扫描电镜观 察发现 :复合纤维内部有少许孔洞、裂纹 ,且随纺丝原液中固含量的增加而减少。 关键词 　胶原蛋白 ; PVA ; 戊二醛 ; 复合纤维 ; 结构 ; 性能 中图分类号:TQ342. 4 　　　文献标识码 :A 　　　 Research on collagenPVA composite fibers with glutaraldehyde as crosslinker WANG Xuejuan , TANG Yi , WU Weiyu , XU Jianjun , YE Guangdou ( The State Key Laboratory of Polymer Materials and Engineering , Sichuan University , Chengdu , Sichuan 　610065 , China) Abstract 　Spinning solution was prepared with collagen and PVA blending by addition of glutaraldehyde as crosslinker. CollagenPVA composite asformed fiber could be produced via wet spinning. After heat drawing , heat setting , and acetalization , the collagenPVA composite fiber was obtained. The composite fiber had strength 3. 74 cNdtex , modulus 44. 60 cNdtex , elongation 31. 30 % and crystallinity 60. 79 %. The value of stick point in water was 105 ℃, and the moisture regain was 8. 9 %. According to SEM photographs , cross section of the composite fiber had a few of holes and cracks , these defects diminished with increasing the sold content of the spinning solution. Key words 　collagen ; PVA ; glutaraldehyde ; composite fiber ; structure ; property 　　近年来 , 以各种生物为原料生产纤维的研究风 力学性能 ,又具有较好的染