瑞典查默斯技术大学碳烟模型.pdfVIP

Combustion and Flame 136 (2004) 270–282 /locate/jnlabr/cnf A phenomenological model for the prediction of soot formation in diesel spray combustion Feng Tao,∗ Valeri I. Golovitchev, and Jerzy Chomiak Thermo and Fluid Dynamics, Department of Mechanical Engineering, Chalmers University of Technology, SE-412 96 Göteborg, Sweden Received 9 December 2002; received in revised form 29 October 2003; accepted 11 November 2003 Abstract A phenomenological soot model coupled with complex chemistry mechanism for the prediction of soot forma- tion in diesel spray combustion is presented. The prototype of the model is one proposed by Leung and Lindstedt in which soot formation is treated by four global stages: particle nucleation, surface growth, surface oxidation, and particle coagulation, each of which is represented by only a few reaction steps. In the present study, the model is modified according to recent literature data. The formation of soot particles is linked with gas-phase chemistry via diacetylene and naphthalene, which are presumed to be indicative species of particle inception/nucleation. The soot surface growth is described using Frenklach et al.’s active site model, and the oxidation mechanism includes both Nagle and Strickland-Constable’s O2 oxidation and Neoh et al.’s OH oxidation models. The soot model inte- grated with the gas-phase kinetics is then applied in multidimensional spray simulations. The KIVA3 code that is widely used in diesel combustion studies is modified and employed for the simulations. The turbulent flow is pre- dicted using the compressible k–ε model, and the turbulence-chemistry interaction handled by a partially stirred reactor model. The IDEA experimental data for n-heptane