废轮胎热解油轻质馏分加氢脱硫反应的本征动力学_余锋.pdfVIP

Vol . 37 No. 2 ( ) 145 2011-04 Journal of East China U niversity of S ien e an d T e hnology ( Natural S ien e E dition) : 1006-3080( 2011) 02-0145-06 余 锋, 邹 滢, 王 慧, 翁惠新 ( 华东理工大学石油加工研究所, 上海200237) : 采用微型固定床反 装置, 选用FH-98 型催化剂, 在催化剂活性稳定阶段且消除内外 扩散影响的情况下, 进行废轮胎热解油轻质馏分加氢脱硫反 本征动力学研究, 并考察了反 温度 ( 563. 15~ 643. 15 K) 反 压力( 1. 0~ 3. 0 M Pa) 对加氢脱硫反 的影响规律结果表明: 提高反 温度和反 压力对加氢脱硫反 有利; 经F 检验及相对误差分析确定建立的动力学模型显著可 信, 用其描述热解油轻质馏分在FH-98 催化剂上的加氢脱硫反 本征动力学是合适的 : 废轮胎热解油; 轻质馏分; 加氢脱硫; 本征动力学 : T Q519 : A Intrinsic Kinetics of Hydrodesulfurization of Light Fraction of Used Tire Pyrolysis Oil YU Feng, ZOU Ying, WA N G H ui, WEN G H ui-xin (Petroleum Processing Research enter, East hina University of Science and Technology , Shanghai 200237, hina) Abstract : Intrinsi kineti s of hydrodesulfurization ( HDS) of light fra tion of used tire pyrolysis oil over the FH-98 atalyst w as studied in a mi ro-fixed bed rea tor during the stage w ith stable atalyst a tivity and w ithout internal and external diffusion. T he effe ts of rea tion temperature ( 563. 15- 643. 15 K) and r ea tion pr essure ( 1. 0- 3. 0 MPa) on HDS w ere investigated. T he results show ed that the in r ease of r ea tion temperature and pressure w as favor able to the HDS rea tion. The kineti model w as signifi antly r eliable through F test and r elative error analysis. T hus, it w as suitable to des ribe the intr insi kineti s of HDS of light fra tion of used tire pyr olysis oil over the FH-98 ataly st . Key words: used tire pyrolysis oil; light fra tion; hy drodesulfurization; intr insi