GPC-分子量及分子量分布测量.pptVIP

* 讲一些关于各个公司利用液相色谱外加GPC组件完成GPC功能，检测器的温度稳定性，进样器的进样体积和液相色谱不同 * The concentration detector responds to concentration, C. The RI detector responds to C times the specific refractive index increment, dn/dc. The MW sensitive detectors respond to MW times some function. For viscometers, this function is [n], the intrinsic viscosity. For light scattering, the response is simply M(C), and for mass spectrometry, the response is 1/M. This is why mass spec. is not very useful for high MW polymers. * For a given MW, a branched polymer will have a lower intrinsic viscosity and smaller size. We can ratio the