若干羰基化反应研究新进展-催化学报.PDF

2010 Chinese Journal of Catalysis Vol. 31 No. 1 文章编号: 0253-9837(2010)01-0001-11 DOI : 10.3724/SP.J.1088.2010.90526 综述(特约) : 1~11 若干羰基化反应研究新进展 刘建华, 陈 静, 孙 伟, 夏春谷 中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室, 甘肃兰州 730000 摘要: 直接在化合物分子内引入羰基的羰基化反应是当前绿色化学化工研究的前沿领域之一, 也是实现 C1 资源高值化利用的重 要途径. 综述了胺/氨基醇类化合物氧化羰化、环氧化合物氢酯基化、碘代芳烃的羰化 Suzuki 偶联、羰化 Sonogashira 以及双羰 基化等重要羰基化反应的研究状况, 特别是结合本课题组近年来在该领域中的工作, 并对羰基化反应的发展及应用前景进行了 展望. 关键词: 胺类化合物; β-氨基醇; 氧化羰化; 环氧化合物; 氢酯基化; 碘代芳烃; 羰化偶联; 双羰化 中图分类号: O643 文献标识码: A Recent Progress in Research of Some Carbonylation Reactions * * LIU Jianhua , CHEN Jing, SUN Wei, XIA Chungu State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu, China Abstract: Carbonylation, the direct incorporation of carbonyl functionality into organic molecules, is one of the frontiers of green chemistry and one of the important transformation pathways of utilization of C resources. The recent research progress of oxidation carbonylation of 1 amines/β-amino alcohols, alkoxycarbonylation of epoxides, carbonylative Suzuki coupling, carbonylative Sonogashira, and double carbon- ylation of aryl iodides has been presented, focusing on the carbonylation reactions studied by us in the past few years, with 8 1 references. The development and application prospects for carbonylation have been also discussed. Key w