横向加热石墨炉原子吸收法直接测定香精香料中的痕-现代仪器与医疗.PDF

检验检测 2014年  第20卷   第1期 横向加热石墨炉原子吸收法直接测定 香精香料中的痕量砷、铅 1 1 2 2 高韬 　 熊文 　候宏卫 　唐纲岭 （1.红塔烟草（集团）有限责任公司，云南　玉溪　653100 ；2. 国家烟草质量监督检 验中心，郑州　450001 ） [ 摘　要 ]　建立横向加热石墨炉原子吸收法直接测定香精香料中砷、铅的方法。香精香料不 经过消解前处理，用2% 硝酸稀释后直接进样至石墨炉内进行检测，本法可称取大量样品以提 高样品溶液中待测元素的含量，获得更好的准确度，同时避免了前处理过程中样品受到污染和 损失。用氯化钯和硝酸镁及硝酸镍分别做铅、砷的混合基体改进剂，消除基体干扰并提高灰化 及原子化温度。检测样品铅的相对偏差3% ，回收率在95.5% ～101.5% 之间；砷的相对偏差 3%, 回收率在85.3% ～86.5% 之间。 [ 关键词 ]　石墨炉原子吸收；香精香料；直接测定；砷；铅 中图分类号：O657　文献标识码：B　文章编号：2055-5200(2014)01-072-05 Doi:10.11876/mimt201401019 Direct determination of trace As and Pb with transversely heated GFAAS　GAO 1 1 2 2 Tao , XIONG Wen , HOU Hong-wei , TANG Gang-ling . 1.Technology Center of Hongta （ Tobacco(Group) Co.Ltd.,Yuxi,Yunnan 653100 2.National tobacco quality supervision ， ； and inspectioncenter, zhenzhou 450001 ， ） [Abstract]　Developed a method for the direct determination of Pb and As in fragrence and flavor . The flavors and fragrances samples were dispensed into a graphite tube dilut with 2% HNO3 without digested, in this way ,large sample amount was permiter to get the better accurate result,and avoid the pollution and lose during the digest process.A mixture of PdCl + Mg(NO ) as the chemical modifiers 2 3 2 in Pb and Ni(NO3)2 in As can reduce the Matrix Interference and get a higher pyrolysis and atomiz temperature.The recoveries of Lead in the range of 95.5%~101.5%with RSD3% A in the range of ， 95.5%~101.5%with RSD3% [Key words]　GFAAS; direct determination; Flavors and Fragrances;As;Lead