水淬含钛高炉渣的盐酸浸取研究-钢铁钒钛.PDFVIP

第33卷第5期 钢摇 铁摇 钒摇 钛 Vol郾33,No郾5 2012年10月 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 IRON STEEL VANADIUM TITANIUM 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 October2012 水淬含钛高炉渣的盐酸浸取研究 张摇 鹏,刘代俊,毛雪华,陈建钧 (四川大学化工学院,四川 成都610065) 摘摇 要:钛铁矿经过高炉炼铁以后,大量的钛进入炉渣中。 为了对水淬含钛高炉渣中的Ti进行回收利用,采用盐酸 法对高炉渣常压下浸取提钛。 试验结果表明,浸取过程中,高炉渣中大量的Ca、Mg、Al、Ti进入到液相中;在试验考 察的影响因素中,原料粒度对浸出率没有影响,而盐酸浓度、反应时间、反应温度、液固比都对浸出率有较大影响; 得到其最佳浸取条件为:反应时间120 min、盐酸浓度大于30%、反应温度90 益、液固比7郾5 颐1以上。 在该条件下, Ti 的浸出率可以达到90%以上。 关键词:含钛高炉渣;提钛;盐酸;浸出;回收利用 中图分类号:X757,TF803郾2摇 摇 文献标识码:A摇 摇 文章编号:1004-7638(2012)05-0006-04 Leaching of Water Quenched Titanium鄄bearing Blast Furnace Slag in Hydrochloric Acid Zhang Peng,Liu Daijun,Mao Xuehua,Chen Jianjun (School of Chemical Engineering,Sichuan University,Chengdu610065,Sichuan,China) Abstract:Following ironmaking process in BF,a great deal of titanium is brought from iron conentrate into slag. In order to recycle the titanium in water鄄quenched Ti鄄bearing blast furnace slag,hydrochloric acid is used in the leaching process. Possible influencing factors on leaching rate are investigated. The result indicates that a large amount of Ca,Mg,Al andTi dissolvesin hydrochloric acid solution in leac鄄 hing process. Among the potential influencing factors investigated in experiments,raw materials size has no influence onTi leaching rate,while hydrochloric acid concentration,reaction time,reaction tempera鄄 ture and ratio of liquid over solid have a pronounced impact on it. The optimum leaching conditions are thus obtained asfollows:concentration of hydrochloric acid of 30% above,residence time for 120 min, ratio of liquid over solid of 7.5 above,and temperature at 90 益. Under the optimum leaching condi鄄 tions,the leaching rate of titaniu