鸟粪石沉淀-协同氧化预处理阻燃剂废水-环境工程学报.pdfVIP

第 11卷　 第7 期 环 境 工 程 学 报 Vol. 11,No.7 2 0 1 7 年 7 月 Chinese Journal of Environmental Engineering July 2 0 1 7 鸟粪石沉淀-协同氧化预处理阻燃剂废水 ∗ 冯莹莹,崔康平 ,王郑,肖霄 合肥工业大学资源与环境工程学院,合肥 230009 摘　 要　 采用鸟粪石沉淀法、Fe/ C微电解-Fenton 氧化组合工艺对阻燃剂废水进行预处理,研究各阶段的最优反应条件。 结果表明:鸟粪石沉淀最优工艺条件为 pH 9.5、HRT =20 min、n(Mg)∶n(P) =1.1∶1,Fe/ C 微电解-Fenton 氧化的最优工艺 + 条件为初始 pH 3.5、HRT =80 min、双氧水(30%浓度)的投加量为 10%。 最优条件下连续运行的出水 COD、TP 和 NH -N 4 的去除率可达70%、97.8%和78.6%左右。 关键词　 阻燃剂废水;鸟粪石沉淀法;Fe/ C微电解-Fenton 氧化;协同氧化 中图分类号　 X783　　 文献标识码　 A　　 文章编号　 1673-9108(2017)07-3997-06　　 DOI:10.12030/ j.cjee.201604206 Flame retardants wastewater pretreatment by struvite precipitation-synergy oxidation ∗ FENG Yingying,CUI Kangping ,WANG Zheng,XIAO Xiao School of Resources and Environmental Engineering,Hefei University of Technology,Hefei 230009,China Abstract　 Flame retardant wastewater was pretreated by struvite precipitation and Fe/ C micro-electrolysis-Fen- ton combination oxidation process. The optimal reaction conditions at each stage were studied. The optimum process conditions for the struvite precipitation stage were:influent pH 9.5,HRT 90 min,and n(Mg)∶n(P)= 1.1∶1.The optimum process conditions for the Fe/ C micro-electrolysis-Fenton oxidation stage were:influent pH 3,HRT90 min,and H O dosage of 10%.With continuous operation under optimal conditions,the total remov- 2 2 + al rates of COD,TP,and NH -N were about 70% ,97.8% ,and 78.6% ,respectively. 4 Key words　 flame retardants wastewater;struvite precipitation;Ferric/