煤焦高温反应非线性特征分析.PDF

第 30 卷 第 23 期 中 国 电 机 工 程 学 报 Vol.30 No.23 Aug.15, 2010 34 2010 年 8 月 15 日 Proceedings of the CSEE ©2010 Chin.Soc.for Elec.Eng. 0258-8013 (2010) 23-0034-06 TK 229 A 470 20 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 煤焦高温反应非线性特征分析 费华，胡松，向军，孙路石，张安超，付鹏，陈巧巧，陈刚 (煤燃烧国家重点实验室(华中科技大学) ，湖北省 武汉市 430074) Study on Nonlinear Characteristics of Coal Char Reaction Under High Temperatures FEI Hua, HU Song, XIANG Jun, SUN Lu-shi, ZHANG An-chao, FU Peng, CHEN Qiao-qiao, CHEN Gang (State Key Laboratory of Coal Combustion (Huazhong University of Science and Technology), Wuhan 430074, Hubei Province, China) ABSTRACT: The coal chars combustion as well as 当固体反应转换率小于 0.9 时，ψ 基本上保持不变，而在固 gasification is comparative complex non-catalytic gas-solid 体反应转换率超出 0.9 时，ψ 急剧上升。 reaction. Evolution characteristics of particle structure not only 关键词：煤焦；非催化气固反应；分形随机孔模型；非线性 reflect reactive processes, but also intensify the complicated 结构特征；等温反应 degree of the reactions. In this paper, the random pore model (RPM) structural parameter ψ was modified by fractal theory, 0 引言 and nonlinear characteristics of structural parameter were 颗粒物及焦表面结构以及它在反应过程中的 clarified at various carbon conversions and a new model, 变化是非常复杂的，颗粒相的演化直接影响整个反 fractal random pore model (FRPM), was constructed. 应过程的特征。由于颗粒内部孔隙结构复杂，孔的 Compared with the result of RPM, it was found that fractal