分子印迹微萃取技术的研究进展-色谱.PDFVIP

2012年12月 Vol.30 No.12 December2012 ChineseJournal of Chromatography 1220~1228 专论与综述 DOI:10.3724/ SP.J.1123.2012.08002 分子印迹微萃取技术的研究进展 张凯歌,　 胡玉玲,　 胡玉斐,　 李攻科∗ (中山大学化学与化学工程学院,广东 广州510275) 摘要:微萃取技术是一种将分析物高效萃取富集于微体积的聚合物或有机溶剂中,集采样、萃取、浓缩、进样于一体 的无(少)溶剂、易于与其他技术在线联用的样品前处理方法。 分子印迹聚合物是一种具有强大分子识别功能的材 料,具有高效的选择特异性,可从复杂样品中选择性分离富集目标分析物,在微萃取技术中得到了广泛的应用。 本 文综述了近年来分子印迹微萃取技术的研究进展,包括分子印迹固相微萃取、分子印迹搅拌棒吸附萃取、分子印迹 磁性微球萃取等微萃取技术。 共引用文献75篇。 关键词:分子印迹微萃取;分子印迹固相微萃取;分子印迹搅拌棒吸附萃取;分子印迹磁性微球萃取;综述 中图分类号:O658　 　 　 文献标识码:A　 　 　 文章编号:1000-8713(2012)12-1220-09 Development of molecularly imprinted microextraction techniques ZHANG Kaige,HU Yuling,HU Yufei,LI Gongke∗ (School of Chemistry and ChemicalEngineering,Sun Yat-sen University,Guangzhou510275,China) Abstract:Microextraction techniques can extract efficiently the analytes from a sample matrix tothepolymers or organic solvents of microvolume,and integrate sampling,extraction,con- centrationandinjectionintoonesinglestep. Theyhavetheadvantagesof simple,time-efficient and solvent-free. They have been successfully coupled with a variety of analytical tools,such as gas chromatography and high performance liquid chromatography. Molecularly imprinted polymers have specific recognition ability. They can separate and enrich analytes from compli- cated matrix with high selectivity,and they have great application prospects in complicated samplepreparation. Thisreview summarizestheprogressinthemolecularly imprintedmicroex- traction techniques,including molecularly imprinted-solid phase microextraction,molecularly imprinted-stir bar adsorptive extraction,magneticmolecularly imprintedbeads extraction