混凝土中钢筋锈蚀过程非氧扩散控制试验研究报告(修改稿).docVIP

文章编号：1000-2472(200*)0*-000*-0* 混凝土中钢筋锈蚀过程非氧扩散控制的试验研究 姬永生1,2，申建立2，王磊2，张超2， 耿欧2 （1.中国矿业大学深部岩土力学与地下工程国家重点实验室; 2.中国矿业大学建筑工程学院，江苏 徐州 221008） 摘 要：确定混凝土中钢筋锈蚀过程的控制因素是建立合理、准确的钢筋锈蚀速率模型的先决条件。本文通过恒温干燥试验研究了钢筋锈蚀电流随混凝土孔隙饱和度PS的变化规律，通过未锈浸泡、锈蚀后浸泡、锈蚀后继续自然锈蚀的对比试验研究了3种不同条件下钢筋锈蚀速率变化过程，并进行了浸泡前后钢筋锈蚀产物物相变化的XRD分析。恒温干燥试验的研究结果表明，混凝土内钢筋的锈蚀速率随混凝土孔隙饱和度PS的增大而增大，和氧扩散速率的变化规律截然相反。对比试验研究表明，氯盐溶液长期浸泡下未锈试件即使活化也无法锈蚀，而锈蚀试件却可以继续高速锈蚀3个月以上，从而说明氧仅是混凝土内钢筋开始的锈蚀的必备条件，而不是混凝土中钢筋锈蚀过程的控制因素。XRD分析表明，钢筋一旦已经开始锈蚀（即有锈蚀产物存在），锈蚀产物中FeOOH可以取代氧成为钢筋锈蚀过程阴极反应的新的去极化，即使在饱水条件下，钢筋的锈蚀仍然可以继续进行。 关键词：锈蚀过程；控制因素；孔隙水饱和度；氧扩散；锈蚀产物 中图分类号：TU 375　　　　　文献标识码：A Experimental Study of Process Control of Reinforcement Corrosion in Concrete JI Yong-sheng1,2 SHEN Jian-li2 WANG Lei2 ZHANG Chao2 GENG Ou2 (1.State Key Laboratory for Geomechanics and Deep Underground Engineering; 2.School of Architecture Civil Engineering, China University of Mining and Technology Xuzhou, Jiangsu, CHINA 221008) Abstract: In order to prove the assumption that corrosion rate of steel in concrete is controlled by the diffusion rate of oxygen is reasonable, the effect of Icorr on degree of pore saturation in concrete under a given temperature has been investigated by monitoring corrosion current. A comparison test of corrosion rates of passive steel, active steel in completely water saturated concrete and active steel in atmosphere environment have been investigated. The phase component of corrosion products of steel bars before and after the specimens were immersed into water was measured with the application of the X-ray diffraction analysis technique. The research indicates that the corrosion rate would decrease when concrete dries (the pores are more open and the pathway for oxygen is higher). After the corrosion products are enough, FeOOH in corrosion layer can act as depolarizer instead of oxygen, so the corrosion rate is still very high even if concrete is completely water saturated. The oxygen is one of the factors that influence corrosion rate but is not the