304L不锈钢形变诱导马氏体的X射线衍射分析-中国测试.PDFVIP

第40 卷第6 期 中国测试 Vol.40 No.6 2014 年11 月 CHINA MEASUREMENT TEST November，2014 doi ：10.11857/j.issn.1674-5124.2014.06.008 304L 不锈钢形变诱导马氏体的X 射线衍射分析 董登超， 张 珂， 吴园园， 胡显军 （江苏省（沙钢）钢铁研究院，江苏张家港215625） 摘 要：为准确测定304L 奥氏体不锈钢中形变诱导马氏体的含量，更好地解释该材料中形变诱导马氏体相变机制， 使用X 射线衍射法对一系列形变后的奥氏体不锈钢样品进行研究，采用Rietveld 全谱拟合法对各物相含量进行分 析，并与传统的直接对比法、K 值法进行比较，该法能最大限度克服传统方法的缺点。分析结果显示：304L 奥氏体不 锈钢形变过程中会发生α ′和ε 马氏体相变，且低温形变会加速奥氏体不锈钢中奥氏体相向马氏体相的转变。 关键词：奥氏体不锈钢；形变诱导马氏体；Rietveld 全谱拟合法；直接对比法；K 值法 中图分类号： + ； ； ； 文献标志码： 文章编号： （ ） TG115.22 2 TG142.71 TG111 TM930.12 A 1674-5124 2014 06-0031-04 Determinate deformation-induced martensite content in 304L stainless steel with X-ray diffraction DONG Deng-chao ，ZHANG Ke ，WU Yuan-yuan ，HU Xian-jun （Institute of Research of Iron and Steel in Jiangsu Province ，Sha-Steel Co.，Ltd.，Zhangjiagang 215625，China） Abstract: In order to accurately determinate the deformation-induced martensite content in 304L austenite stainless steel and better explain the phase transformation mechanism ，XRD was employed to investigate a series of deformed samples ，and Rietveld method was adopted to analyze the martensite content. And also the method was compared with the traditional direct comparison method and K-value method. It can be concluded that the defects of traditional methods could be modified by Rietveld method. The results show that γ -austenite would be transformed into α ′-martensite and ε -martensite under deformation and lower temperature could accelerate the phase transform