硬脂酸木薯微晶淀粉酯性质研究及结构表征 structural characterization and study on properties of cassava microcrystalline stearate starch.pdfVIP
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硬脂酸木薯微晶淀粉酯性质研究及结构表征 structural characterization and study on properties of cassava microcrystalline stearate starch
04Ls08-02
10 粮食与油脂 2009年第8期
硬脂酸木薯微晶淀粉酯性质研究及结构表征
1 1 2
李素玲 ,高群玉 ,刘 垚
(1. 华南理工大学轻工与食品学院, 广东广州 510640;2. 中山市质量计量监督检测所, 广东中山 528403 )
摘 要:采用微晶化和干法酯化制备硬脂酸木薯微晶淀粉酯,研究不同低取代度硬脂酸木薯微晶
淀粉酯理化性质,并应用红外光谱和X– 射线进行结构表征。结果表明,淀粉经复合改性后,糊粘
度明显降低,凝沉性变小,透明度增加,淀粉溶解性、乳化性和乳化稳定性得到较大改善;硬脂酸木
薯微晶淀粉酯在3 ,000~3 ,700 cm– 1 处羟基伸缩振动吸收峰强度减弱,酯化反应主要发生在淀粉
分子结构无定型区。
关键词:改性淀粉;微晶化;淀粉酯
Structural characterization and study on properties of cassava
microcrystalline stearate starch
1 1 2
LI Su-ling ,GAO Qun-yu ,LIU Yao
(1. College of Light Industry and Food Science ,South China Univ. of Tech. ,Guangzhou 510640 ,China ;
2. Zhongshan Supervision Testing Institute of Quality Metrology ,Zhongshan 528403 ,China )
Abstract :Cassava microcrystalline stearate starch (CMSS) was prepared through micritization and dry
esterification. The physicochemical properties of low degree of substitution of cassava microcrystalline
stearate starch were studied and also the modern technology of infrared spectroscopy as well as X–ray
diffraction were employed. The results show that after modifying,starch paste viscosity reduces
significantly and retrogradation descends,transparency of starch paste becomes high. The properties
of solubility ,emulsifying ability and emulsifying stability are greatly improved. It is also revealed that
the absorption peak strength of OH stretching vibration decreases nearby 3 ,000~3 ,700 cm– 1 and the
esterification reaction mainly happens at the amorphous region of the molecular structure.
Key words :modified starch ;mic
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