电子材料论文2013.docx

PAGE \* MERGEFORMATIII 聚吡咯导电材料的性能与研究进展综述 摘要 聚吡咯导电材料属于结构型导电聚合物材料。因其合成容易且导电率高，与生物体的相容性较好等特点广泛应用于传感器材料、防腐材料、电极材料、电磁屏蔽材料等。本文介绍了聚吡咯导电高分子材料的结构、导电机理、聚吡咯复合材料分类及其应用领域，综述了近些年来国内外科研工作者对聚吡咯导电高分子材料的研究进展状况。 关键词：聚吡咯，导电性，掺杂，聚吡咯复合材料，应用 Properties and research progress of polypyrrole conductive materials ABSTRACT Polypyrrole conductive materials are structured conductive polymer materials. They are widely used in sensor materials, anti-corrosion materials, electrode materials, electromagnetic shielding materials because of its synthesis and high conductivity, good compatibility with biological characteristics. This article describes the structure of polypyrrole, conductive mechanism of polymers, polypyrrole composite materials classification and its application. And it focuses on the research progress of polypyrrole conductive polymer materials at home and abroad in recent years. Keywords: polypyrrole, conductivity, adulterate, polypyrrole composites, application 目 录  TOC \o 1-3 \h \z \u  HYPERLINK \l _Toc375488498 第1章 绪论  PAGEREF _Toc375488498 \h 1  HYPERLINK \l _Toc375488499 1.1聚吡咯的结构特征及导电机理  PAGEREF _Toc375488499 \h 1  HYPERLINK \l _Toc375488500 1.2影响聚吡咯导电性的因素  PAGEREF _Toc375488500 \h 2  HYPERLINK \l _Toc375488501 1.2.1 氧化剂的影响  PAGEREF _Toc375488501 \h 2  HYPERLINK \l _Toc375488502 1.2.2 掺杂剂种类的影响  PAGEREF _Toc375488502 \h 2  HYPERLINK \l _Toc375488503 1.2.3 温度的影响  PAGEREF _Toc375488503 \h 2  HYPERLINK \l _Toc375488504 1.2.4 其他因素的影响  PAGEREF _Toc375488504 \h 2  HYPERLINK \l _Toc375488505 1.3聚吡咯的制备方法  PAGEREF _Toc375488505 \h 2  HYPERLINK \l _Toc375488506 1.3.1电化学氧化法  PAGEREF _Toc375488506 \h 3  HYPERLINK \l _Toc375488507 1.3.2化学氧化法  PAGEREF _Toc375488507 \h 3  HYPERLINK \l _Toc375488508 1.4聚吡咯的掺杂  PAGEREF _Toc375488508 \h 4  HYPERLINK \l _Toc375488509 1.4.1 化学掺杂  PAGEREF _Toc375488509 \h 4  HYPERLINK \l _Toc375488510 1.4.2 电化学掺杂  PAGEREF _Toc375488510 \h 4  HYPERLINK \l _Toc375488511 第2章 聚吡